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Biennial reports ETC Biennial Report 1996
[ ETC > Publications > Biennial Reports > 1994-1996 ]





ETC Biennial Report
April 1, 1994 to March 31, 1996

Report Series No. DO 1-95/96
Environmental Technology Centre
Technology Development Directorate



Environmental Technology Centre

Table of Contents

NOTICE
ABSTRACT
1.0 ORGANIZATIONAL STRUCTURE AND DIVISIONAL MANDATES
2.0 AMBIENT AIR MONITORING AND NAPS NETWORK
3.0 TOXIC CHEMICAL MEASUREMENTS
4.0 MEASUREMENT OF EMISSIONS FROM STATIONARY SOURCES
5.0 MEASUREMENT OF EMISSIONS FROM MOBILE SOURCES
6.0 SUPPORT TO SPILL RESPONSE
7.0 SPILL MEASUREMENT, BEHAVIOUR AND EFFECTS RESEARCH
8.0 SPILL COUNTERMEASURES R&D
9.0 INTERNATIONAL TRANSFER OF CANADIAN TECHNOLOGY
10.0 TECHNOLOGIES FOR DECONTAMINATING WATER
11.0 TECHNOLOGIES FOR DECONTAMINATING SOILS
12.0 CO-ORDINATION OF SCIENCE AND TECHNOLOGY
13.0 COMMERCIALIZATION OF ENVIRONMENT CANADA’S PATENTED MICROWAVE-ASSISTED PROCESS (MAPTM)
14.0 DEVELOPMENT OF MAP ANALYTICAL METHODS AND INSTRUMENTATION
15.0 DEVELOPMENT OF INDUSTRIAL APPLICATIONS OF THE MAP TECHNOLOGY


APPENDICES

A Mission and Roles of the Environmental Technology Centre
B List of Patents, Papers and Reports
C List of ETC Employees and Telephone Numbers
D List of Abbreviations


NOTICE

The co-ordination of the preparation of this Biennial Report was done by Caroline Ladanowski who would like to thank Dr. Merv Fingas, Fred Hendren, Francine Payne, Monique Punt, Dr. David Thornton, Richard Turle, and Don Williams for their assistance during its preparation.

This report has not undergone detailed technical review by the Environmental Protection Service and the content does not necessarily reflect the views and policies of Environment Canada. Mention of trade names or commercial products does not constitute an endorsement for their use.

This unedited version is undergoing a limited distribution in order to transfer the information to people working in related studies. This distribution is not intended to signify publication and, if the report is referenced, it should be cited as an unpublished report of the Environmental Protection Service.

Any comments on the contents of the report or requests for additional copies should be directed to:

Office of the Director
Environmental Technology Centre
Environmental Technology Advancement Directorate
Environmental Protection Service
Environment Canada
Ottawa, Ontario
K1A OH3
Tel: (613)991-5633
Fax: (613)998-1365

EMAIL INTERNET: [email protected]
EMAIL DOTS: PAYNEF@AM@AESOTT



ABSTRACT

The Environmental Technology Centre (ETC) of Environment Canada was established in 1975 to provide technical and R&D support for the department's many activities. The Centre deals primarily with the measurement of air pollutants in ambient air and air pollutants emitted from mobile and stationary sources, the analysis of a wide variety of organic and inorganic compounds in diverse sample matrices, the cleanup of leaking hazardous waste sites, and the response to pollution emergencies such as oil and chemical spills. Most of the R&D work and some of the technical support services are undertaken in collaboration with the public, private and academic sectors. Some R&D work is also done in co-operation with international partners.

At the Environmental Technology Centre, the Director's Office is responsible for the overall direction of the ETC programs and for central services such as administrative and computing support. The laboratory and field capabilities of the Centre are distributed among the following six divisions:
  • Analysis and Methods
  • Emergencies Engineering
  • Emergencies Science
  • Microwave-Assisted Processes
  • Mobile Sources Emissions
  • Pollution Measurement

The rationale and results of the major activities conducted at ETC from April 1, 1994 to March 31, 1996 are described in this ETC Biennial Report. A list of reports and papers presented or published during this reporting period is included.


RESUM�

1.0 ORGANIZATIONAL STRUCTURE AND DIVISIONAL PROGRAM MANDATES

1.1 Environmental Technology Centre
1.2 Pollution Measurement Division (PMD)
1.3 Mobile Sources Emissions Division (MSED)
1.4 Analysis and Methods Division (A&MD)
1.5 Emergencies Science Division (ESD)
1.6 Emergencies Engineering Division (EED)
1.7 Microwave-Assisted Processes Division (MAP)


1.1 Environmental Technology Centre

The Environmental Technology Centre (ETC) of Environment Canada (EC) was established in 1975 to provide specialized technical and R&D support for the department’s many activities. The Centre deals primarily with the technologies for the measurement of air pollutants in ambient air and air pollutants emitted from mobile and stationary sources, the analysis of a wide variety of organic and inorganic compounds in diverse sample matrices, the cleanup of leaking hazardous waste sites and the response to pollution emergencies such as oil and chemical spills. Most of the R&D work, and some of the technical support services, are undertaken in collaboration with the public, private and academic sectors. Some R&D is also done in co-operation with international partners. A significant part of the work is performed by contractors working on- and off-site.

The Annual Departmental Reference Level scientific budget of the Centre (including salaries, capital, and operations and maintenance) is about $8 million. In an average year, another $3-5 million is received through cost-sharing Joint Project Agreements (JPAs) with collaborators in the public and private sectors. JPAs usually involve another $5-10 million through work-sharing agreements. The Centre has a staff of about 100 with typically another 50 to 60 workers on-site: contractors, students, post-doctoral fellows and visiting researchers. The official “Mission of the Environmental Technology Centre” is included in Appendix A.
  • Project results are documented in informal (unedited) manuscript reports, and formal (edited) reports available in both official languages. In addition, staff contribute technical and scientific papers to journals and to proceedings of conferences and workshops. A list of reports and papers from the Centre during this review period is given in Appendix B and a list of staff members and phone numbers is given in Appendix C. A list of abbreviations is given in Appendix D.
  • At the Centre, the Director's Office is responsible for the overall direction of the ETC programs and for central services such as administrative and computing support. In addition, coordination of special issues is undertaken on occasion. The laboratory and field capabilities of the Centre are distributed among the following six divisions.

1.2 Pollution Measurement Division (PMD)
  • PMD is responsible for co-ordination of the operation of the federal-provincial National Air Pollution Surveillance (NAPS) Network, which consists of 380 air-monitoring instruments at 130 sampling stations located in 52 major urban areas in Canada.
  • The Division also evaluates and develops new ambient air pollution measurement technology in support of the NAPS network and priority issues such as Long-Range Transportation of Air Pollution (LRTAP), air toxics, climate change and smog.
  • The Division's source monitoring activities include: development and updating of Reference Methods for measurement of emissions from stationary sources in support of the Canadian Environmental Protection Act (CEPA) Regulations and Guidelines; development of new emissions-measurement methods in response to emerging priority issues; evaluation of commercially available monitors to measure stack emissions on a real-time basis; application of emissions measurement methods at-source to satisfy the Department's need for information for a variety of purposes, including technology development and evaluation.

1.3 Mobile Sources Emissions Division (MSED)
  • The Division undertakes emission testing of a wide variety of mobile sources, from cars, buses and trucks to ships, planes and trains.
  • The MSED conducts the vehicle emissions testing for the federal government's compliance audit program for new light duty vehicles offered for sale in Canada. This joint Transport Canada/Environment Canada program evaluates new vehicles for exhaust/evaporative and particulate mass emissions to determine compliance with standards and regulations under the Canadian Motor Vehicle Safety Act.
  • The Division investigates alternative fuels and alternative engine technologies to determine their potential impact on Canadian air quality and to provide emission factors for predicting total national emissions.
  • The MSED undertakes joint government/industry programs to develop new technologies or to optimize existing systems, which will result in performance improvements and energy and emission reductions.
  • The Division conducts testing programs to update Canadian fleet-emissions estimates, including in-use vehicle monitoring, effects of ambient temperature on emissions, and the results of emissions-control tampering. As a result of testing of this nature, the government develops regulations and guidelines to protect the Canadian environment more effectively.
  • The MSED provides a unique technical advice and assistance program which includes limited testing for external clients. The program includes evaluation of fuel-saving devices and the provision of technical assistance to the general public, governments, industries, and institutions.

1.4 Analysis and Methods Division (A&MD)
  • The Division determines a variety of organic and inorganic compounds in diverse sample matrices, such as from air-pollution-related sources, contaminated soils, hazardous wastes and other residues. Analytical method development is also undertaken to ensure the most appropriate procedures are available for specific sample types and to support the development of environmental regulations. The Division is also engaged in Regulatory Compliance and Quality Assurance activities in support of internal and external programs.
  • The Organic Laboratory measures ultra trace levels (ppt, ppq) of many organic compounds with particular emphasis on the analysis of polychlorinated dibenzo-p-dioxins (PCDD), polychlorinated dibenzofurans (PCDF), polychlorinated biphenyls (PCB), polycyclic aromatic hydrocarbons (PAH) and other priority pollutants. A specially designed and operated Organic UltraTrace Laboratory is used for sample preparation and analysis of these toxic pollutants. The laboratory also carries out analytical projects in support of national programs, like the Enforcement Program; develops Analytical Reference methods to support CEPA regulations; designs and implements interlaboratory studies to validate analytical procedures; and manages quality assurance/quality control (QA/QC) and method development programs to ensure data generated by contract labs are of the highest quality.
  • The Inorganic Laboratory develops and applies ultratrace methods for the determination of elements and anions in air particulates. The principal techniques used are X-ray fluorescence and ion chromatography. X-ray fluorescence is used for the analysis of forty elements (aluminum up to lanthanum and lead). Ion chromatography is used for the analysis of ten major anions including the "acid rain" components, that is sulphate and nitrate, and ten cations (alkali metals, ammonium, and earth alkali metals). The Laboratory organizes and participates in round robins at the national or international level to promote improvements in the capabilities of Canadian analytical laboratories. The Laboratory also performs legal analyses for the regional offices of Environment Canada, and provides advice on analytical equipment and methods to private industry and governmental laboratories.
  • The Good Laboratory Practice (GLP) Compliance Monitoring Unit provides support to the New Substances Division of the Commercial Chemicals Evaluation Branch by inspecting Canadian laboratories which provide data in support of New Substances Notifications, by maintaining information on the compliance status of overseas GLP laboratories, and by auditing specific laboratory studies at the request of domestic or overseas regulatory authorities. In addition, the Unit is responsible for GLP program development, for supporting GLP activities of the Organisation for Economic Co-operation and Development, and for program administration in the Environmental Protection Service (EPS) and Environmental Conservation Service (ECS) of the Program on Energy Research and Development.
  • The Method Development and Application Section is responsible for the forecasting of EC analytical method needs and development of new toxicological methods required for regulation. Priority analytical chemistry methods and performance-based-method guidance are developed in conjunction with the Laboratory Manager’s Committee. Aquatic and sediment toxicology methods are developed in conjunction with staff from EC regional, provincial and private-sector laboratories. The Section also develops audit checklists and guidance on data interpretation for methods required under Fisheries Act and CEPA regulations. As well, the Section puts a significant level of support towards the Canadian Association for Environmental Analytical Laboratories (CAEAL) laboratory accreditation program in the area of environmental toxicology.

1.5 Emergencies Science Division (ESD)
  • The Division undertakes research on the properties, behaviour, and effects of spilled hazardous materials, and on the effectiveness and environmental benefits of in situ countermeasures such as spill-treating agents, burning, and bioremediation. Such information is used to develop research and operational models which predict the behaviour and fate of untreated and treated spills.
  • R&D is also performed on techniques for measuring contamination in air, water, and soil at spill sites and on technologies for airborne remote sensing of spills.
  • The Division prepares technical spill-response guidelines and manuals for use by emergency response personnel and contingency planners, and serves as the primary centre of scientific advice on pollution emergencies to the regional offices of Environment Canada and others. For spills of national concern, this role includes direct involvement in response operations through the provision of information and predictions about spill behaviour, fate and effects, and airborne remote sensing services, on-site specialized sampling and analytical support. Further, training in the use of personal protection equipment and portable hazard-level monitoring equipment is provided to Departmental emergencies personnel and to other responders.
  • The Division co-ordinates the preparation of the quarterly Spill Technology Newsletter and the annual international Arctic and Marine Oilspill Program (AMOP) Seminar and the Technical Seminar on Chemical Spills (TSOCS).

1.6 Emergencies Engineering Division (EED):
  • The Division undertakes engineering research, development, and demonstration work on technologies for cleaning up contamination caused by pollution emergencies, such as oil or chemical spills, and insecure hazardous waste sites. This work includes R&D on, and evaluation of, sorbent performance and containment/recovery/disposal equipment for response to oil and chemical spills in marine and non-marine environments. It also includes the development, dissemination, and use of testing protocols for evaluating spill-response equipment in the laboratory and the field.
  • The Division develops and maintains a range of prototype mobile cleanup equipment which is used, in co-operation with others, to demonstrate and adapt innovative methods for on-site mitigation of water or soil contamination which is difficult to handle using conventional techniques.
  • The Division serves as the primary centre of specialized engineering advice on pollution emergency cleanup to the regional offices of Environment Canada and others. For spills of national concern, this role can include direct involvement in cleanup operations through the provision of on-site expertise and unique mobile water- or soil-decontamination equipment. It also involves the overseas transfer of Canadian technologies in collaboration with the private sector.

1.7 Microwave-Assisted Process (MAP) Division :
  • The Division has been formed at ETC to accelerate the development and commercialization of various applications of Environment Canada’s patented Microwave-Assisted Process (MAPTM). This Division is responsible for the activities associated with the environmental protection applications of MAP, such as the analysis of contaminated material and the removal of contaminants from soil, as well as clean industrial process applications, such as the extraction of high value-added products from a variety of matrices, including wastes.


2.0 AMBIENT AIR MONITORING AND NAPS NETWORK

2.1 National Air Pollution Surveillance (NAPS) Network
2.2 Support to the NOX/VOC Plan
2.3 Fine Particulates and Canadian Acid Aerosol Measurement Program (CAAMP)
2.4 Research in Application of Ion Chromatography and Capillary Electrophoresis
2.5 VOC Monitoring and Research Program
2.6 PAH and Dioxin/Furan Monitoring Program


2.1 National Air Pollution Surveillance (NAPS) Network

The NAPS network is a joint program of the federal and provincial governments for monitoring and assessing the ambient air quality at 130 air monitoring stations in 52 urban centres across Canada. Air quality data for the criteria pollutants - sulphur dioxide, carbon monoxide, nitrogen dioxide, ozone, suspended particulates and other pollutants, including particulate lead, sulphate, and nitrate were collected to the end of 1994, validated and archived in the NAPS database.

Two annual reports of hourly, daily, monthly and annual statistics on air quality, and its status with respect to the national air quality objectives for the years 1992 and 1993, were prepared and published. Various air quality data reports were provided to the State of Environment (SOE) Reporting staff for preparation of the SOE Urban Air Quality Indicator Bulletin and to the Organization for Economic Co-operation and Development bi-annual compendium of environmental data. Technical information and reports were provided to the Pollution Data Analysis Division, the Atmospheric Environment Service (AES), regional offices, provincial agencies, the U.S. Environmental Protection Agency (EPA), the World Health Organization and non-government organizations (universities, consultants, industries).

Technical support on network operations and quality assurance was provided to the NAPS provincial agencies and two regional offices. This support included supplying and/or certifying over nineteen monitoring instruments, providing calibration materials (136 cylinders) to eight provinces, auditing monitoring stations in six provinces, completing four NAPS interagency calibration comparisons, completing an international comparison of the ozone reference standard with the US National Institute for Science & Technology (NIST) and operating three monitoring stations in the National Capital Region. A document of the QA/QC guidelines for the NAPS network was prepared and distributed to the network agencies.

The fourth NAPS Management meeting for all provincial agencies of the Network was organized and held in Ottawa. Provincial and federal monitoring programs were reviewed and recommendations developed regarding the technical support provided by ETC.

2.2 Support to the NOX/VOC Plan

The purpose of the NOX/VOC (Volatile Organic Compound) Science Program of the Canadian Council of the Ministers’ of Environment (CCME) NOX/VOC Management Plan is to improve the scientific knowledge and understanding of ozone formation in Canada in order to develop appropriate and effective NOX and/or VOC control strategies. The Science Program was started in February 1992 and is charged with producing a State of the Science Assessment Report by mid 1996. The Data Analysis Working Group (DAWG), which is chaired by ETC staff, is one of eight multistakeholder (provincial government, federal government, non-governmental environmental, university and industry) working groups. A detailed DAWG report has been drafted which addresses the research questions noted below.
  1. What are present levels of NOX, VOCs and O3 (urban/suburban/rural/remote) and temporal and spatial variations?
  2. What are the long term trends in NOX, VOCs and O3?
  3. What are background O3 concentrations in Canada?
  4. What are the atmospheric conditions and processes that lead to high O3 levels in Canada?
  5. What can be learned about atmospheric source-receptor relationships from empirical data? Are results consistent with model predictions?
  6. How much ozone and precursors at a given location is the result of long-range transport, either from Canadian or U.S. sources?
  7. What is the effect of elevation on ground level O3 and how should this be addressed in network design?
  8. What is the contribution of stratospheric ozone to tropospheric ozone (and vice versa)?
  9. What is the role of clouds/water vapour in ozone formation and transport?

The NAPS database was the primary source of information required to generate the DAWG Report. The database includes all Canadian observations of ozone (O3), nitrogen dioxide (NO2), nitric oxide (NO) and nitrogen oxides (NOX) for the years 1980 to 1994. Ozone data for 150 rural and urban United States sites for the years 1980 to 1994 are also incorporated into the database. The NAPS database has been converted to ORACLE 7 and is located on a UNIX work station system in Dorval. It has been developed in a common format with the AES Climate Archive (ATIS/CAP) and both air quality and meteorological data can be accessed through common routines by EC staff throughout Canada.

ETC staff also participated in completion of reports for the Ambient Air Monitoring Working Group, the Inventory Working Group and the Vegetation Effects Working Group of the NOX/VOC Science Program. ETC staff provide advice and assistance to the Science Assessment Working Group, the Health Objectives Working Group and the various modelling working groups that are delivering the 1996 Science Assessment.

2.3 Fine Particulates and Canadian Acid Aerosol Monitoring Program (CAAMP)

The Canadian Acid Aerosol Measurement Program (CAAMP), which formally began in 1992, assists in the study of the health effects of airborne particles and particle acidity. CAAMP is a joint effort of AES, ETC and the Air Quality Health Effects Research Section of Health Canada. Daily monitoring for total particulate loading, particle acidity and detailed characterization of particles have been carried out at nine eastern urban and rural locations. Additionally, a fine and coarse particle characterization monitoring program has been carried out at another 12 urban sites which are located in all provinces of Canada.

ETC’s participation includes:
  • installing and maintaining dichotomous samplers for the measurement of fine and coarse particles, and denuder filter pack systems for the measurement of acidity at several stations;
  • selecting and training operators;
  • arranging sample shipping and handling;
  • determining major cations and anions in filter and denuder extracts by ion chromatography (IC);
  • measuring acidity (pH) of the fine fraction of aerosols; and
  • database maintenance, data reporting, data summarization and data interpretation.

A number of research publications have been produced in cooperation with Health Canada and others in Environment Canada. Results show that elevated airborne particulate levels are associated with statistically significant increases in mortality and in hospital admissions in Canada. A number of detailed health studies are being carried out by researchers in Toronto, Montreal and Saint John with the support of ETC staff. A CCME Clean Fuels Task Force used the monitoring results to calculate that reductions in particules from transportation sources would accrue health benefits totalling 11 to 28 billion dollars over the period 1997 to 2020.

2.4 Research in Application of Ion Chromatography and Capillary Electrophoresis

Ion chromatography (IC) with suppressed conductivity detection has been used for the measurement of the chemical composition of atmospheric aerosols. A recent R&D project involved improved analysis of cations and anions by a multi-IC system using a single autosampler. Currently 14 inorganic and organic anions, and 11 inorganic cations can be simultaneously determined by the developed procedure. New self-regenerating suppressors and cation separation columns were utilized, resulting in lower detection limits, shorter analysis time and lower reagent consumption.

IC is not the only method for separating ionic species. Capillary electrophoresis (CE), where separation is mainly based on differences in analyte size and charge at a given pH, has been successfully introduced as a new separation technique for the analysis of inorganic and organic ions. Research has been continued to investigate the usefulness of CE in the analysis of inorganic and organic anions and cations in atmospheric aerosols. The CE, IC and photometric techniques were compared for response stability of instruments, detection limits, accuracy, precision, analysis cost and time for the analysis of nitrate and sulphate. Statistical analysis of the results showed that there were no systematic differences between the three techniques. Furthermore, high efficiency, speed and economy of analysis are among the many attributes that makes CE an excellent tool for such analysis. The CE method may also be useful for comparison of the results when two independent methods are required for control of the quality of analytical work. Work is underway to implement CE methods for the determination of major ions in atmospheric aerosols and other environmental samples. Since this technique has application to other areas of environmental analysis, it was agreed by the EC Laboratory Managers’ Committee that ETC would take the lead for this area of research.

A study was undertaken to investigate the feasibility of using CE with a new electrolyte system for the analysis of alkali metal, alkaline earth metal cations and ammonium. With the developed electrolyte composition, it was also possible to determine manganese and cadmium, and short-chain aliphatic amines. This technique may be applicable to atmospheric aerosols.

In conjunction with Carleton University, a method based on capillary electrophoresis with amperometric detection has been developed for the speciation of mercury. The resolution provided by CE allows the separation of inorganic and organomercury species in 7 minutes. The amperometric signal is linearly proportional to the Hg2+ concentration over three orders of magnitude, with detection limits at the sub-part-per-billion level (i.e., 0.2 ng/mL).

The usefulness of micellar electrokinetic capillary chromatography, a form of CE, was investigated for the separation of 16 polynuclear aromatic hydrocarbons (PAHs) on the U.S. EPA priority pollutant list. The research showed that the effective separation of 15 PAHs could be achieved by using sodium taurodeoxycholate micellar buffer with the addition of 30% acetone. The capability of the developed separation system was demonstrated in the analysis of PAHs in ambient air extracts.

2.5 VOC Monitoring and Research Program

The major achievement of this program is an extensive high quality database of systematic observations. It is the most extensive long-term data record of its kind in North America. It is now possible to produce nationally representative trend data for a large number of species including those important in climate change. Results from the program have been used extensively in the CEPA Priority Substance List 1 (PSL1) assessment program and in the PSL2 selection process. The ambient air monitoring program supports both the ground-level ozone and toxics issues, and uses the existing federal/provincial infrastructure of the NAPS network. There are over 40 active urban and rural VOC sampling sites in Canada. During the summers of 1994 and 1995, intensive sampling programs were conducted at five rural sites to define better the contribution of anthropogenic and biogenic sources to measured levels of hydrocarbons important in ground level ozone.

ETC has participated in the international non methane hydrocarbon intercomparison experiment and assisted a number of agencies with development and standardization of VOC analytical methods. Methods have been successfully adapted for use in measuring stationary and mobile source emissions, to characterize landfill gas and to assess the environmental impacts of oil burning. On-going support in the field of toxic VOC research has been provided to the provinces, municipalities, Environment Canada regional offices, EPS Headquarters, other government departments and universities. Hundreds of requests for data on ambient concentrations of measured species are received annually from researchers in the federal, provincial and municipal levels of government, academics and the private sector.

A detailed report on VOC and NOX in Vancouver showed a poor match between emission-derived VOC-to-NOX ratios and ambient-derived ratios. Since most of the discrepancy is expected to be due to underestimated VOC emissions from motor vehicles, a detailed study of actual motor vehicle emissions was carried out in the Cassiar Connector tunnel in Vancouver during the summer of 1993. This study was the first of its kind in Canada and has proven very useful in obtaining a more accurate picture of total emissions from motor vehicles. A series of reports and papers were prepared on the Cassiar study and the results were used in preparation of the Emission Inventory Work Group Report for the NOX/VOC Science Assessment.

Data were collected in the monitoring program on over forty VOC of concern because of toxicity. A detailed report on benzene levels in Canada was prepared to support the CEPA Stategic Options Process for benzene. Data on compounds selected as candidates for PSL2 were provided to Health Canada and Environment Canada staff. Detailed data analyses are being carried out on 1,3-butadiene and formaldehyde, which are being “fast-tracked” in the PSL2 assessment process.

A joint research project with AES scientists to study isoprene emissions from Canadian forests has been carried out with field studies in Prince Albert National Park (as part of the international BOREAS project) and at Camp Borden, Ontario. The work was sponsored by the NOX/VOC Science Program and was designed to improve knowledge of emission rates of biogenic VOC from Canadian tree species under meteorological conditions representative of Canada. The research team pioneered the measurements of tubes and amounts of hydrocarbons released by tree species grown in Canada. The experimental design involved the participation of chemists (to measure hydrocarbon concentrations), plant physiologists (to characterize emission rates from foliage) and micrometeorologists (to characterize turbulent transfer and to measure environmental variables governing hydrocarbon emissions at both leaf and canopy levels).

The field experiments allowed testing of leaf-cuvette, gas-exchange systems coupled with gas chromatography and mass spectrometry for measuring tubes and amounts of hydrocarbons released by foliage. A novel computer-controlled cryo-concentrator for field analyses was constructed and operated during the field sampling and a real-time isoprene analyzer, based on the flame-ionization-detection (FID) principle was designed and fabricated. Calibration standards for a-pinene and b-pinene were also developed and these chemicals were quantified in samples collected at the sites. Assistance was provided to researchers at Agriculture Canada involved in flux measurement of VOC from crops

2.6 PAH and Dioxin/Furan Monitoring Program

In cooperation with Environment Canada regional offices and provincial environment agencies, the PAH and PCDD/PCDF measurement program was extended to include twenty-six rural and urban sites across Canada. PCDD/PCDF data are being shared with researchers in the USA to determine contributions of various industrial sectors on ambient levels.

Data from the Windsor-Walpole Ontario sites were used to assess impacts of PCDD/PCDF emissions associated with the operation of the Greater Detroit Municipal Incinerator (GDRRA). It was clear from plots of PCDD/PCDF concentration versus wind direction that, although elevated concentrations at each of the sites occurred with winds from the direction of the GDRRA, other wind directions (especially south-southwest and southwest at the two Windsor sites) were associated with high PCDD/PCDF concentrations. Based on all sampling days, it was estimated that the GDRRA incinerator contributed 7 to 26% of the mean measured PCDD/F toxic equivalent (TEQ) concentrations at the three sites.


3.0 TOXIC CHEMICAL MEASUREMENTS

3.1 Development of a Reference Method for PCBs
3.2 Development of a Reference Method for ODS
3.3 Development of a Method for Analysis of Dioxin-like PCBs
3.4 Development of an Improved Method for Nitro-PAH Analysis
3.5 Dioxin Quality Assurance (QA) Audit
3.6 National Round Robin Studies with CAEAL
3.7 Development of Analytical Method for UDMH
3.8 Development of Analytical Method for Xylidine


3.1 Development of a Reference Method for PCBs

An analytical Reference Method has been developed in support of the various CEPA regulations that govern the use and disposal of PCB-containing materials. This document consists of two parts: Part I describes a screening method using the gas chromatograph-electron capture detector (GC-ECD) technique with a simple cleanup to determine the level of PCBs; and Part II is a confirmation method employing GC-MS (mass spectropgraph), carbon-13 labelled surrogates (isotope dilution) and a thorough cleanup to identify unambiguously and quantify total PCBs. Confirmation analysis is required only if the PCB concentration determined by GC-ECD is greater than 60% of the regulatory limits.

The method is written in a performance-based format. Mandatory procedures written in bold type must be followed. Procedures that are not written in bold type may be modified, as long as performance criteria are met.

The second and third draft of the proposed Reference Method were distributed to more than 40 Canadian industrial and government laboratories for comment. The final draft of the Reference Method has been completed and will be published shortly.

3.2 Development of a Reference Method for ODS

The CEPA Ozone Depleting Substance (ODS) Regulations initiated in response to the Montreal Protocol were administered by compliance monitoring activities to verify the prohibition on the manufacture, sale and importation of commercial products containing regulated chlorofluorocarbons (CFCs).

In support of the ODS regulations, an analytical method using a solid-phase microextraction (SPME) technique to determine five CFCs (F11, F12, F113, F114 & F115) in aerosol products has been developed. SPME coupled to GC-MS provides a fast, unequivocal and quantitative analysis with minimal sample preparation requirements. Another method, using a Short Path Thermal Desorption Unit and GC-MS to determine CFCs in foams, has also been developed.

3.3 Development of a Method for the Analysis of Dioxin-like PCBs

Some non-ortho, mono-ortho and di-ortho substituted polychlorinated biphenyls have been recognized as the most toxic components in commercial PCB formulations because of their structural similarity to 2,3,7,8-TCDD, which is the most toxic dioxin. Furthermore, because of their higher concentrations and persistence in the environment, the toxic impacts of these compounds may be more significant than those from the chlorinated dioxins and furans.

A method has been developed for the separation and enrichment of the three non-ortho, eight mono-ortho and two di-ortho substituted PCBs from Aroclor formulations and environmental samples. The fractionation was accomplished using HPLC with a 2-(1-pyrenyl) ethyldimethylsilyated silica column. A GC-MS with an optimized temperature program was used for quantitation. Hexane, pentane, cyclohexane, iso-octane and 2-propanol were tested as mobile phase for the isolation of the 13 dioxin-like PCBs in an Aroclor 1242/54/60 (1:1:1) mixture. The average separation efficiency of the toxic PCBs from an Aroclor mixture was 99.5% with a standard deviation of 4.5%. The average method detection limit was 8 pg/ul.

3.4 Development of an Improved Method for Nitro-PAH Analysis

Nitro-polycylic aromatic hydrocarbons (N-PAH) are mutagenic and some compounds of the group are carcinogenic for experimental animals. Diesel engine exhaust has been the major emission source for N-PAH. However, studies on N-PAH from other emission sources and in ambient air are limited. The lack of adequate instrumental sensitivity or selectivity, and limited availability of native and isotope-labelled standards are some key factors that have discouraged researchers from monitoring N-PAH compounds in the environment.

An improved method using HRGC-HRMS (HR=high resolution) and isotope dilution techniques was developed. This method has been applied satisfactorily for the determination of selected N-PAH in diesel engine exhaust and ambient air samples. Of eleven targeted mono- and di-nitroPAH, isomers of nitroanthracene, nitrofluoranthene and nitropyrene have been detected consistently in the exhaust and ambient air samples at significant levels. Detection limits for diesel particles and ambient air are in low ng/g and pg/m3 ranges, respectively.

In collaboration with NIST, several reference materials were characterized for PAH and nitro-PAH. These materials are SRM-1650 of diesel particulate, SRM-1975 of diesel extract (new) and SRM-1649 of urban dust.

3.5 Dioxin Quality Assurance (QA) Audit

A dioxin QA audit program was set up in support for audit of the CEPA pulp and paper mill regulations. Each of the five EC Regions provided analytical data from selected effluent samples from pulp mills. Laboratories that had performed the analyses were contacted to submit corresponding QA/QC data for audit. Laboratories that failed to meet the quality criteria requirement, or did not follow the Reference Method, were identified and recommendations for improvement were provided. At the request of EC Regional offices, investigations were carried out to resolve any discrepancy between lab results on split samples.

3.6 National Round Robin Studies with CAEAL

The Canadian Association of Environmental Analytical Laboratories (CAEAL) is a nonprofit organization whose mandate is to certify that laboratories can supply reliable analytical data. CAEAL is currently assessing the ability of participating laboratories to perform an analysis of PCBs-in-oil, and anions (F-, CL-, NO3- & SO4-) and metals (Cd, Cu, Pb & Zn) on air filters. This Association will certify laboratories that are able to provide acceptable data on the analysis of these types of samples.

ETC has been providing round robin samples for the certification program since 1992. Each set of samples consists of four samples fortified with target analytes at different concentrations. In 1995, approximately 30 labs were certified for air filters and approximately 50 labs were certified for PCBs in oil analysis.

3.7 Development of an Analytical Method for UDMH

Visiting Ukrainian researchers, in conjunction with their ETC colleagues, developed a novel analytical method for determining 1,1-dimethyl hydrazine (UDMH) in soil and water using GC-MS. UDMH with nitric acid is commonly used to propel SS-19 missiles, which form the bulk of Ukraine’s nuclear arsenal. UDMH is a degradation product of Daminozide, which is a pesticide commonly used to improve the size, colour, and storage features of fruit. UDMH is carcinogenic and it may degrade to nitrosodimethylamine (NDMA) which is even more toxic and carcinogenic. UDMH, like hydrazine, is a polar compound and is not easily determined by GC-MS. The novel method is based on the derivatization of UDMH to hydrazone compounds followed by GC-MS measurement. The method is highly sensitive and can be used to determine low concentration levels of UDMH residues in soil and water.

3.8 Development of an Analytical Method for Xylidine

Visiting Latvian researchers, in conjunction with their ETC colleagues, developed an analytical method for determining xylidine in soil and water using a simple ultraviolet (UV)-visible spectrophotometric method in the field or laboratory. Samin fuel, which contains mainly xylidine, is used to propel missiles which form the bulk of Latvia’s arsenal. Xylidine is also used in manufacturing azo-dyes and in synthetic rubber production. It is similar to aniline, a frequently used and spilled chemical. The method is based on the reaction of xylidine with a colouring agent to shift the absorbance signal from the UV region towards the visible zone of the spectrum to minimize matrix interferences. The soil matrix was determined to have no significant effect on xylidine measurements because it does not absorb at the analyte wavelength (760 nm). The effects of the overall soil sorption capacity and pH on xylidine recovery and remediation processes were also studied.


4.0 MEASUREMENT OF EMISSIONS FROM STATIONARY SOURCES

4.1 Support to DOE Regulatory and Inventory Programs
4.2 Support of Greener Technologies


4.1 Support to DOE Regulatory and Inventory Programs

4.1.1 Reference and Recommended Methods for Source Testing
4.1.2 National Inspection Plan & Training of CEPA Inspectors
4.1.3 Quality Assurance and Quality Control
4.1.4 Canadian Trace Emissions Management Project (CTEMP)
4.1.5 NOx/VOCs Management Plan
4.1.6 Emissions Monitoring Technology Transfer
4.1.7 Climate Change
4.1.7.1 Field Measurements of Greenhouse Gas Emissions
4.1.7.2 Organic Emissions from Landfill Gas (LFG)
4.1.7.3 Methane Fugitive Emissions


4.1.1 Reference and Recommended Methods for Source Testing

Revisions were made to the dioxin/furan and PCB Reference Method (EPS 1/RM/2) to reflect the change of materials and analytical improvements over the past few years. This Method is also used for the determination of dioxins and furans and polycyclic aromatic hydrocarbons from municipal, hospital and hazardous waste incinerators and combustors.

ETC continued to evaluate the applicability of the ambient air SUMMA� canister method for determining VOCs from vented landfills, landfill gas incinerators, recovery boiler flue gases and dissolving tank vents and a proprietary CFC recovery unit. The canister method offers a simple, viable, and more flexible alternative to the volatile organic sampling train (VOST) method. A study is also being performed on the long term stability of stack gases stored in a SUMMA� canister.

A Recommended Method for the measurement of ammonia was prepared. This method was needed both to serve as a back-up and to validate the continuous monitoring results for the ammonia slip after the catalyst from the Selective Catalytic Reduction (SCR) study in Point Tupper, N.S.

ETC is preparing a Recommended Method for the measurement of CO and NOx from gas turbines. This method will be used to support the NOx/VOC Initiative N307.

ETC has issued a Recommended Method for the measurement of fugitive methane emissions from natural gas transmission and distribution facilities, such as gate and distribution stations and residential and commercial meter sets. This method will be used by the natural gas industry to conduct their own evaluations. The results will be used to establish methane leakage emission factors for Canada. Methane is a ‘greenhouse’ gas.

4.1.2 National Inspection Plan & Training of CEPA Inspectors

ETC continues to assist EPS Regional offices responsible for the implementation of the National Inspection Plan by reviewing and commenting on compliance testing proposals/plans, pre-test QA/QC, on-site witnessing/auditing of compliance tests, validating sampling data, and reviewing and recommending on the acceptance of the final compliance test reports. Recent joint ETC-Regional projects included compliance/enforcement activities associated with the Secondary Lead Smelter Release Regulations, and the Mobile PCB Destruction and Treatment Regulations. Examples include the Triwaste Thermal Phase Separator performance testing in Cremona, Alberta, the Makinsons orphaned site in Newfoundland, the Cape Breton municipal solid waste (MSW) incinerator in Sydney, Nova Scotia, and the Victoria General hospital incinerator in Halifax, Nova Scotia.

4.1.3 Quality Assurance and Quality Control

Work has commenced on an comprehensive QA/QC Manual for manual stack sampling, although part of this information has already been disseminated to the Regions and provinces. This document will incorporate all aspects of compliance testing such as auditing, witnessing, calibration and safety.

A collaborative study was completed with the Communaut� Urbaine de Montr�al regarding the effect of wind tunnel dimensions on the calibration of pitot tubes.

Techniques for the construction, calibration and use of critical orifices in the field were distributed to the Regions and the provinces. The critical orifice offers a relatively simple technique for verifying the dry gas meter (DGM) coefficient in the field.

4.1.4 Canadian Trace Emissions Management Project (CTEMP)

In response to the U.S. Environmental Protection Agency’s concern over toxic releases from power generating stations, the U.S. Electrical Power Research Institute (EPRI) developed a computer model known as PISCES (Power Plant Integrated Systems Chemical Emissions Study) that would predict the impact of fuel type, additives and equipment configuration on toxic emissions. However, it soon became apparent that the PISCES emission data were out-of-date, of questionable quality, and not compatible because of the different measurement protocols used. In support of EPRI's effort to update and improve the database, the Canadian Electrical Association (CEA) is sponsoring a parallel initiative known as the Canadian Trace Emissions Management Project (CTEMP). The purposes of CTEMP are to:
  • harmonize Canadian and U.S. toxic measurement protocols;
  • provide more up-to-date emission data to EPRI; and
  • adapt the PISCES model to Canada.

The CEA-sponsored CTEMP project, which is partly funded by Environment Canada, is divided into two phases, each being led by a Canadian utility company. The overall project team comprises of process and measurement experts from Ontario Hydro, Nova Scotia Power, Alberta Power, CANMET and Environment Canada.

During Phase 1, ETC participated as a member of the CTEMP team by providing expertise in emission measurement and by assisting in the completion of a Canadian measurement protocols document.

During Phase 2, ETC, in cooperation with the Industrial Sectors Branch and Nova Scotia Power, participated in an air emission survey at the coal-fired power plant in Lingan, Nova Scotia, in late October 1993. The ETC testing team was responsible for measuring the concentrations of volatile and semi-volatile organic compounds at the electrostatic precipitator (ESP) inlet and the stack.

4.1.5 NOX/VOCs Management Plan

Recognizing urban smog as a pollutant causing health problems, CCME has implemented a joint federal-provincial NOx/VOC Management Plan to control the amount of smog precursors, including nitrogen oxides (NOx), being released into the atmosphere. In cooperation with the Oil, Gas and Energy Division and the Regions, ETC has devoted considerable resources to the planning and implementation of source testing surveys at the following sites:
  • Nova Scotia Power's SCR Pilot Plant at Point Tupper (N305)
  • Lime and cement kilns in Qu�bec (N306)
  • Recovery boiler in Qu�bec (S302/S103)

4.1.6 Emissions Monitoring Technology Transfer

Continuous emissions monitoring (CEM) is the real-time measurement and reporting of air emissions from stationary sources such as industrial chimneys and landfill sites. To address an increasing need for CEM technology transfer, ETC and the Oil, Gas and Energy Division offered a CEM course in February of 1993. Since then, six additional courses have been held in various locations across Canada with three more courses expected in 1996/1997. About 25 participants attended each three-day workshop covering: the principle and operation of a CEM system; the requirements of CEM technology for compliance with the proposed CCME NOx/VOCs guidelines; and the use of CEM technology for pollution prevention through better process monitoring and control. The participants also have hands-on work assignments using some of the state-of-the-art CEM analyzers in ETC's source-measurement laboratories and mobile unit. In addition to the transfer of source-measurement technology from ETC to industry and other levels of governments, the course provides the private- and public-sector attendees with a forum to share their views and experience on an informal basis, and to establish better understanding for future cooperation.

ETC has made several presentations regarding protocols and performance specifications for continuous monitoring of gaseous emissions from thermal power generation to utilities, technical seminars and the Regions.

4.1.7 Climate Change

4.1.7.1 Field Measurements of Greenhouse Gas Emissions

Canada is committed to a comprehensive consideration of all greenhouse gases (GHGs). While data on fuel-related carbon dioxide (CO2) emissions are considered reliable, data on other CO2 sources and other GHGs require verification. Additional data are required for stationary point and area sources of methane (CH4) and nitrous oxide (N2O), in particular. In cooperation with the Air Issues Directorate, ETC assisted in the development, refinement and verification of current emission factors for GHG emissions from area and point sources through field measurements. ETC's work to date include the following:
  • commercially available GHG analyzers were evaluated, selected for purchase and tested at ETC laboratories to ensure that the instruments met specifications and quality assurance requirements;
  • bench-scale method development was carried out to simulate field testing conditions and to evaluate the different ways of sample collection; and
  • a field testing program was carried out at a local landfill site. A testing report is being prepared based on the data analysis.

A final report was completed which covered the measurement of methane and carbon dioxide from selected landfills. The measurement program covered short- and long-term, and spatial variations of landfill gases. These data will be used to establish emission factors for Canadian landfills as well as the validation of the U.S. EPA model for landfill emissions.

4.1.7.2 Organic Emissions from Landfill Gas (LFG)

As an extension of the greenhouse gas measurement program, ETC embarked on a program to measure VOCs from vented landfills. Earlier grab samples indicated a wide assortment of aliphatic and aromatic compounds (including halogenated species) from the vents of landfill gas collection systems. In some cases these gases are flared, which may produce semi-volatile organic species such as PCDDs/PCDFs and PAHs.

This study looked at the long term variation of VOCs in LFG, variation between sites and organic profile before and after flaring. The performance of existing landfill incineration facilities, with respect to the destruction of organic compounds was also evaluated. Dioxins, furans and PAHs were also determined from the exhaust of a LFG incinerator. Study sites included the Regional landfill at Trail Road in Ottawa and four landfills in the Toronto Metropolitan Area. Target pollutants also included CO2 and CH4.

4.1.7.3 Methane Fugitive Emissions

A joint project agreement was initiated with Gas Technology Canada to quantify fugitive methane emissions from natural gas transmission and distribution facilities such as gate and distribution stations and residential and commercial meter sets. Variables to be tested in the program include ambient conditions, operating gas flow and pressure, type of fitting, age and condition of components, and pre- and post-maintenance sampling. The results will be used to establish methane leakage emission factors for Canada. ETC has also issued a Recommended Method to allow the industry to conduct its own evaluations.

4.2 Support of Greener Technologies

4.2.1 Canadian Biomass Fluid Bed (CANMET) Demonstation Project
4.2.2 Pulp Mill Waste Sludge Incineration and Salt Hog Combustion


4.2.1 Canadian Biomass Fluid Bed (CANBFB) Demonstration Project

Asea Brown Boveri (ABB) invited ETC to participate as a "scientific partner" in the Canadian Biomass Fluid Bed Demonstration Project. The estimated cost of this project is $2.3 million. Other participants in this project include the Avenor Inc. Thunder Bay mill (host facility), CANMET, University of Toronto and the Pulp & Paper Research Institute of Canada (PAPRICAN). The objective of this project is to evaluate the combustion of biomass/sludge mixtures such as de-inking sludges, bark and salt hog/salty wood in a commercial-scale Bubbling Fluid Bed incinerator.

ETC reviewed the Project Description and forwarded comments to the Project Manager. Technical guidance was provided to ABB for design of the test plan matrix, selection, operation and installation of ABB’s flue gas CEM system and siting criteria for manual sampling. A preliminary survey was conducted, and recommendations were forwarded to ABB. ETC will conduct the emission testing during FY96/97.

4.2.2 Pulp Mill Waste Sludge Incineration and Salt Hog Combustion

ETC continues to participate in research, development and demonstration projects involving existing and state-of-the-art "green" industrial process and pollution control technologies. ETC is involved in another R&D initiative to investigate dioxin emissions from salty wood wastes. Participants in this program include PAPRICAN, CANMET, Industry Canada and Environment Canada. The objectives of this program are:
  • to determine the factors affecting the concentration of PCDDs/PCDFs in emissions from boilers burning salt-laden wood wastes;
  • to develop control strategies to minimize these emissions; and
  • to assess dioxin control equipment and technologies, and conduct pilot-plant- and/or full-scale trials.

ETC conducted a critical review of a proposed research program, and is providing technical support to CANMET regarding the source sampling.


5.0 MEASUREMENT OF EMISSIONS FROM MOBILE SOURCES

5.1 Support to Regulatory and Inventory Programs
5.2 Support of Greener Technologies


5.1 Support to Regulatory and Inventory Programs

5.1.1 Compliance Audits and Investigations under the MVSA and QA/QC Programs
5.1.2 Speciation of the Hydrocarbon Compounds in Light-Duty- Vehicle Exhaust Emissions
5.1.3 Joint Program with Consumer and Corporate Affairs to Evaluate Control Devices and Additives
5.1.4 Marine Vessel Emissions
5.1.5 Airport Mobile Sources Evaluation
5.1.6 Preliminary Investigations of Emissions from Small Utility
5.1.7 Pollution from Out-board Motors
5.1.8 In-flight Aircraft Engine Exhaust Emissions
5.1.9 Heavy-Duty Engine Exhaust Emissions Characaterization
5.1.10 In-Use Vehicles Off-cycle and Evaporative Emissions
5.1.11 Vehicle Emissions at Curb Side
5.1.12 Effect of Vehicle Operation on Underground Parking Garages


5.1.1 Compliance Audits and Investigations under the MVSA and QA/QC Programs

ETC, in collaboration with Transport Canada, annually conducts exhaust emission, evaporative emission and fuel consumption tests on a fleet of approximately 35 new-model light-duty passenger cars and light-duty trucks. The purpose of the laboratory testing is to audit emissions compliance with the federal standards, under the Motor Vehicle Safety Act (MVSA), for total hydrocarbons (THC), carbon monoxide (CO), oxides of nitrogen (NOx), particulate mass (PM) and evaporative total hydrocarbon emissions. In addition, this testing allows accurate calculation of fuel consumption for comparison with the values provided by the manufacturers. The testing includes exhaust emission measurements in the facility’s test chamber at -7oC and 24oC. To support this work, ETC participates in vehicle emissions testing and reference-gas cross-correlation programs with the major automobile manufacturers and with the U.S. EPA. ETC also provides test facilities and testing/engineering support to joint industry/government investigations for non-compliant vehicles. Of the vehicles tested in the program for 1995, approximately 10% of the vehicles exceeded either the exhaust emission standards or the fuel consumption values as determined by the manufacturers.

5.1.2 Speciation of the Hydrocarbon Compounds in Light-Duty-Vehicle Exhaust Emissions

ETC, in collaboration with Transport Canada, has been involved in a program since the 1993-vehicle-model-year to enhance the knowledge of toxic emissions from mobile sources for future development of federal exhaust emissions standards. This work has involved characterizing the exhaust stream of light-duty vehicles, including volatile organic compounds, semi-volatiles, carbonyls and specific target compounds (with emphasis on PSL compounds). Technical reports have been prepared and presented on a fleet of twenty 1993 vehicles and twenty-five 1994 light-duty vehicles. The 1995 vehicle test program will be completed during the spring of 1996 and will include cold temperature testing and characterization of the exhaust emissions.

5.1.3 Joint Program with Consumer and Corporate Affairs to Evaluate Control Devices and Additives

In collaboration with the Marketing Practices Branch of Consumer and Corporate Affairs, ETC conducts engineering evaluations and occasional laboratory testing of products that are being marketed for the purpose of reducing exhaust emissions and fuel consumption from mobile sources. The reports from the evaluations are utilized as background documents in the event of legal action and ETC provides expert testimony on behalf of the Crown. The involvement with the Marketing Practices Branch has been maintained at the same level for the past number of years. Technology evaluations on behalf of other government groups, industry and the public, however, have increased significantly. The data from this additional work also represents a bank of knowledge for the regulatory body.

5.1.4 Marine Vessel Emissions

ETC, in collaboration with the Transport Canada Strategic Development Centre and the Canadian Coast Guard, completed a report in 1995 on Phases One and Two of a study om emissions from the Canadian registered commercial marine vessels. The propulsion and hotel exhausts, and emissions from the loading, transporting and unloading of petroleum products were measured. Additional collaborative work is planned for 96/97, whereby ETC will investigate potential emissions control hardware and monitoring systems for these applications.

5.1.5 Airport Mobile Sources Evaluation

ETC, in collaboration with Transport Canada, conducted testing in 1994 at MacDonald Cartier Airport (Ottawa) to characterize the exhaust emissions from airport mobile sources, including aircraft engines, service vehicles, auxiliary power units, and passenger taxis. The collaborative program was extended in 1995 to demonstrate oxidation catalyst technology for diesel engines on an airplane tug and a snowplow. The demonstration program, including field exhaust emission testing, will continue in 96/97.

5.1.6 Preliminary Investigations of Emissions from Small Utility Engines

An exhaust emissions test program was conducted on a small number of utility engines including a 5-Hp general purpose engine, a 3-Hp lawnmower, a 5-Hp snowblower engine and a large grass mower engine. The engines were tested using the U.S. EPA protocols for utility engines. The results essentially corroborate the limited existing literature and indicate that the exhaust emissions from these sources are several factors greater than those from an average light-duty vehicle on an equivalent fuel-usage basis. A project is proposed for 96/97 to expand the inventory of engines and to investigate the impact of reformulated fuels on these sources.

5.1.7 Pollution from Out-board Motors

Limited emissions testing conducted in the USA in the early eighties indicated that exhaust emissions from outboard motors were significantly worse than utility engines. For one hour of out-board motor operation, the mass emissions are comparable to an average light-duty car travelling 500 miles. As these engines have a long life, the contribution to the deterioration of both air and water quality could be significant. To enhance knowledge about this source of pollution, ETC constructed a tank with a computer-controlled engine-loading system, and developed a test methodology for the characterization of both air and water emissions. Preliminary testing to verify the system operation has been conducted on a state-of-the-art four-stroke 9.9-Hp engine. A test program has been established for the evaluation of a variety of different engine types during 96/97.

5.1.8 In-flight Aircraft Engine Exhaust Emissions

During the joint program with Transport Canada to quantify pollution from airport mobile sources, ETC developed a test system to measure real-time exhaust emissions from in-service jet engines. This technology was adapted during 1995 to have the capability to be installed on-board an aircraft for remote sampling of the exhaust emissions from one of the jet engines during actual in-flight operation (i.e., startup, taxiing, takeoff, climbout, cruise). Transport Canada, in collaboration with the ETC, has designed and undertaken the modifications of one of the jet engines on a government-owned Citation corporate jet for the installation of the sampling probes and connections to the interior of the aircraft. Final inflight system verifications are planned for the beginning of 96/97 prior to commencing the program.

5.1.9 Heavy Duty Engine Exhaust Emissions Characterization

ETC and the Transportation Systems Division established a joint project to determine the contribution of heavy-duty engines to air toxics in Canadian cities. A complete characterization of the exhaust emissions from two typical engines used in heavy-duty urban buses (Detroit Diesel 6V92) and in heavy-duty trucks (Detroit Diesel Series 60) began in the spring of 1996, with the work planned to be completed in 1996/97. The testing consists of conducting transient engine testing on a 500-Hp electric dynamometer to collect samples for volatile and semi-volatile organic compounds, polycyclic aromatic hydrocarbons and related nitrated compounds, and trace metals.

5.1.10 In-use Vehicle Off-cycle and Evaporative Emissions

ETC organized and conducted a laboratory test program to investigate the exhaust and evaporative emissions from in-use light duty gasoline vehicles. The results indicated that the evaporative emissions ranged from compliance with the federal standards applicable for the model year of the vehicle to a factor of 8 times greater than this level. Of the 20 vehicles in the program, 15 did not meet their respective evaporative emissions standard. For the exhaust emission standards, excluding the vehicles over 80,000 km, 42% did not comply with respective federal standards for one or more of the regulated emissions.

5.1.11 Vehicle Emissions at Curb Side

A collaborative effort with Carleton University and Health Canada, and support from the City of Ottawa, was initiated in the summer of 1994 to measure mobile source exhaust emissions at curb level, at three locations in downtown Ottawa having high volumes of commuter traffic. The objective of this work was to provide a detailed analysis of the contribution of mobile sources to urban pollution. Samples were collected for the analysis of volatile and semi-volatile organic compounds, carbonyls, trace metals, particulate mass, polycyclic aromatic hydrocarbons, and regulated emissions at each site during four periods (07:30-09:00, 11:30-13:00, 15:30-17:00 and 22:00-24:00), during each day of the work week for a period of four weeks. The data from this work are being used by Carleton University to develop a model for urban centre air quality deterioration based on mobile source emissions at street level.

5.1.12 Effect of Vehicle Operation on Underground Parking Garages

ETC provided support to Health Canada to determine the impact of vehicle operation on the air quality in underground garages by measurements in three underground garages in Ottawa during two periods of heavy vehicle traffic (morning and afternoon rush hours). The emission measurements included speciation of the hydrocarbon compounds, carbonyls and particulate mass. At the completion of the program, the data were transferred to Health Canada for a health impact analysis. ETC prepared a summary report which indicated that carbon monoxide, carbon dioxide, volatile organic compounds and carbonyls were found to be significantly higher than typical outdoor ambient air. For example, levels of 1,3-butadiene, benzene and formaldehyde were found to be approximately 100, 50 and 15 times higher, respectively, than typical levels in outdoor air.

5.2 Support of Greener Technologies

5.2.1 Alternative/Reformulated Fuels
5.2.2 Development of Emission Control Technologies
5.2.3 Alternative Engines/Vehicles


5.2.1 Alternative/Reformulated Fuels

Low Reid Vapour Pressure Fuels

A collaborative program with Transportation Systems Division and Petro Canada, which was designed to investigate low Reid Vapour Pressure (RVP) fuels, was completed during this period. Four identical pairs of vehicles were tested at 24oC and -6.6oC to determine the impact on the emissions (both exhaust and evaporative) while operating on five different gasolines. Four of the fuels were gasolines with decreasing RVPs (i.e., 10.5 to 7.5 psi). A fifth fuel was added to the program as a reformulated gasoline produced by a Canadian refiner. The exhaust was speciated for volatile and semi-volatile organic compounds and carbonyls.

Alternative Fuel Conversion System Durability

A demonstration program was initiated during this period to study the durability of commercially available alternative fuel conversion systems. The Transportation System Division and ETC collaborated on this work with vehicles provided by Canada Post, Ottawa-Carleton Transit Authority, and Natural Resources Canada (NRCan). ETC organized and coordinated the conversion of the transit authority vehicles and the department’s vehicles to ensure that the three basic forms of conversion (i.e., mechanical system with no feedback, mechanical system with electronic feedback and a fuel-injection system) were included. Testing was initiated in the fall of 1995, with the in-service operation and quarterly exhaust emissions testing to be conducted for one year.

Canadian Tar Sands Reformulated Gasoline

_The Western Research Centre (formerly known as CANMET) in Devon (Alberta), US DOE and ETC initiated a joint test program to evaluate the exhaust and evaporative emissions from two US, highly reformulated research gasolines (Phase-2 California reformulated fuel and the US Federal Reformulated gasoline) and a prototype Canadian reformulated gasoline based on an Alberta tar sands product. ETC initiated testing, in the spring of 1996, on two vehicles to compare the exhaust emissions from these reformulated fuels to that of an average commercially available unleaded gasoline. The testing consists of partial exhaust and evaporative emissions characterization at 24oC and partial exhaust emissions characterization at -6.6oC. The US DOE laboratory at Bartlesville, Oklahoma, will conduct parallel testing on 9 different vehicles without the emissions characterization, cold temperature testing or evaporative emissions work.

Natural Gas/Diesel Dual Fuel Urban Bus

_An urban bus with a diesel engine was evaluated at ETC for exhaust emissions and performance after being converted to operate on a dual-fuel system of natural gas and diesel fuel. This cost- sharing project with an engineering consulting firm and the system inventor was conducted to determine if this particular system could reduce the exhaust emissions normally associated with the operation of this form of engine on diesel fuel. The results were not conclusive, as the fuel-management system was not optimized. This allowed both fuels to enter the engine intake at all times, resulting in overfueling and high emissions.

Biodiesel Additives Based on Canola Oil and Soya Bean Oil

Two projects were completed during this period, which involved the evaluation of biodiesels based on methyl soyate from canola oil. The first was a joint project with the Potash Corporation of Saskatchewan to evaluate neat and 50% blends of methyl and ethyl soyate combined with No.2 commercial diesel fuel. The objective of the test project was to determine whether the addition of methyl soyate would reduce the particulate emissions from underground mining vehicles. The neat ethyl fuel was run to determine the engine performance and the emissions from the neat fuel. In addition to the biodiesel, an oxidation catalyst was installed to determine if the additional control hardware would enhance the emissions reduction. The results did not indicate significant reductions in exhaust emissions for the small diesel engine used for the program, even with 1 to 2 degrees reduction in fuel-injection timing. However, the project did not provide for any form of system optimization.

The second project involved the US National Biodiesel Board in a joint project to study a biodiesel consisting of 20% methyl soyate (based on soya bean oil) and 80% No. 2 certification diesel, in combination with an oxidation catalyst and changes in the fuel-injection timing. The laboratory testing was conducted on two urban buses having different engine configurations. The process consisted of a number of combinations of fuel, catalyst and fuel-injection timing, with the results indicating a reduction in particulate mass and oxides of nitrogen with the biodiesel fuel, oxidation catalyst and a 1� degree retardation of the fuel-injection timing.

NRCan Alternative-Fueled Fleet

ETC continued their joint program with NRCan to evaluate the new alternative-fueled vehicles added to the NRCan fleet. The testing included the production Chrysler liquid propane injection van. The exhaust emission results were all within the regulated standards for gasoline vehicles. The results from this program to enhance the inventory of emissions from alternative-fueled vehicles. A more research-oriented project was conducted on a light-duty diesel-powered truck which had been adapted to operate on two fuels (i.e., diesel fuel and blends of hydrogen). The hydrogen from an on-board generator was directed into the intake manifold at a controlled rate as a replacement for a percentage of the diesel fuel. ETC’s evaluation indicated that the generator system was providing only a very small quantity of hydrogen, resulting in the vehicle operating on almost 100% diesel fuel.

_Ethanol Fuels for Utility Engines

To investigate a technology for reducing the exhaust emissions from utility engines, ETC operated two identical 5-Hp engines over a period of 250 hours. One was operated on commercial unleaded gasoline and another on low blends of ethanol fuel up to 50%. An ethanol blend of 30% resulted in the best emissions and performance. The preliminary results indicate that the engine operating on this blend ran smoother, and with more horsepower, than the gasoline-only engine, which had to be rebuilt twice during the testing.

Ethanol Blends for Heavy-Duty Diesel Engines

A potential method for reducing particulate mass and oxides of nitrogen emissions in heavy-duty diesel engine exhaust is to add a blending agent that is compatible with diesel fuel and that will operate in a compression-ignition cycle. Ethanol alcohol has these characteristics, if blended in small percentage volumes with a base commercial diesel fuel. To determine the impact of the addition of ethanol alcohol on the performance and exhaust emissions of a heavy-duty diesel engine, ETC initiated a program to test an average two- and four-stroke engine on blends of 5, 10, 20 and 30% ethanol/diesel fuel. During the testing of the two-stroke bus engine, volatile organic compounds and carbonyls were measured, as well as the regulated emissions, over a transient engine-test cycle. The preliminary data suggested that the engine would operate without any noticeable difference with up to 20% alcohol. Blends of higher alcohol content resulted in engine stumble and hesitation at higher speed. At this point, the engine would require modifications to the fuel-management system to accommodate the different characteristics of the alcohol. The four-stroke engine is scheduled to be tested using the same protocols during 96/97.

5.2.2 Development of Emission Control Technologies

Heavy-Duty Engine Oxidation Catalysts and Diesel Particulate Filters

As a continuation of a collaborative program initiated in 1993 with the Ottawa-Carleton Transit Authority, Englehard, Engine Control Sytems, Ministry of Transportation of Ontario, and NRCan, ETC conducted tests on urban buses having different types of retrofit emissions control technologies. With the phaseout of Donaldson particulate filters from the program, two new technologies were introduced: diesel particulate filters and oxidation catalysts fabricated by Englehard, and dedicated diesel fuel oxidation catalysts from Engine Control Systems. Twenty buses in the Ottawa transit fleet have been equipped with these components and are being tested at ETC on a regular basis to determine the effectiveness of the components over time. The preliminary results indicate reductions in particulate mass and total hydrocarbons by up to 30% with the use of the oxidation catalyst.

‘Tall Oil’ Biodiesel for Heavy Duty Engines

‘Cetane Enhancer’ is derived from ‘tall oil’, a co-product of the pulp and paper industry, by a process developed by the Energy Research Laboratories (formerly known as CANMET) in Bell’s Corner (Ontario). Arbokem, the sole Canadian licensee for this product, with support from BC Chemical, formed a consortium with NRCan and ETC to investigate the potential use of this product as a blending agent for a biodiesel fuel. A series of heavy-duty engine tests were conducted at ETC on blends of ‘cetane enhancer’ (ranging from 10% to 100%) and a diesel fuel supplied by Petro Canada. Vehicle tests were also completed on light heavy-duty trucks provided by Canada Post and urban buses provided by the Ottawa-Carleton Transit Authority. Inconclusive results were obtained using the Petro Canada diesel fuel base. Further testing was conducted using a No. 2 certification diesel fuel as the base fuel with 20 and 40% cetane enhancer. The preliminary results indicated reductions in some regulated exhaust emissions compared to the PetroCanada-based biodiesel fuel.

Biodiesels with Oxidation Catalysts for Exhaust Emissions Reduction

Previous work at ETC indicated that a combination of a 20% blend of methyl soyate and certification diesel fuel with an oxidation catalyst and retarding the fuel-injection timing by 1.5 degrees resulted in reductions of the following bus exhaust emissions over the New York City Cycle: 32% for HC, 38% for CO, 2% for NOx, 7% for particulate mass, and 44% for soluble organic fractions. To determine if further reductions could be obtained using similar technologies, without retarding the fuel-injection timing which increases CO2, ETC implemented a study with methyl soyate and ‘cetane enhancer’ from ‘tall oil’. The program investigated the emissions from an urban bus engine, with and without an Engine Control Systems dual catalyst, while operating on 20% and 40% blends of methyl soyate/diesel fuel and ‘cetane enhancer’/diesel fuel.

Oxidation Catalysts for Medium Duty Trucks

A collaborative program with Engine Control Systems to demonstrate oxidation catalysts for medium-duty diesel vehicles was initiated in December 1994, with units being installed on two Stock school buses in the Ottawa area. The buses have been tested three times and are scheduled for a final laboratory evaluation in early 1996. The initial emissions results indicate a consistent reduction in particulate mass of approximately 30%, as well as reductions in total hydrocarbons and carbon monoxide. In the fall of 1995, the program was expanded to include medium-duty delivery trucks supplied by program participants (Brewers Retail of Ontario and Canada Post). Testing will continue until December 1996.

Nerus Composite Material Engine Components with Ceramic Coatings

The introduction of engine components made from composite materials coated with ceramic sprays has the potential for reducing both fuel consumption and exhaust emissions. Nerus, a company involved in composite materials with ceramic sprays, negotiated a joint project with the Quebec Regional office of Environment Canada, the Municipality of Montreal and a transportation/railway company to evaluate this technology on heavy-duty engines. ETC is providing support to this development by conducting the laboratory vehicle testing on the buses and trucks, and the field testing on railway engines. The initial testing was conducted during the spring of 1996 with the remainder of the evaluation to occur during 1996/1997.

Natural-Gas Continuous-Feedback Fuel-Injection System

The Saskatchewan Research Council, supported by NRCan, developed a natural-gas fuel-injection system based on a more responsive continuous fuel-management-feedback system. The results are exhaust emissions which are equivalent to the low-emission-vehicle (LEV) standards proposed by California. ETC participated in this work by supporting the exhaust emissions testing to optimize the fuel system. The work included evaluating catalysts, certification and pipeline fuels testing and the effect of air-fuel ratios. Additional support for continuing this work is being sought from Suzuki and General Motors.

Optimization of an Alternative Fuel System for Production Vehicles

GFI Control Systems Ltd. purchased the natural gas fuel-injection technology developed as a collaborative Canadian government/industry project during the late 1980’s. GFI Control Systems Inc. entered into a program with ETC to conduct exhaust emissions and performance testing in an effort to optimize the technology for vehicles manufactured by Ford. After the successful conversion of each representative vehicle and emissions testing at regular intervals up to 100,000 miles, the results are being presented to Ford with the goal of becoming one of Ford’s Qualified Vehicle Modifiers using this Canadian technology.

In conjunction with the Ford Qualified Vehicle Modifiers program, ETC was providing support on a cost-recovery basis to GFI Control Systems to obtain certification for their natural gas system in California. For this work, ETC conducted a speciation of the hydrocarbons in the exhaust emissions in order to determine the non-methane organic gases for the determination of ozone-forming potential.

Diesel Engine NOx-Reduction Catalyst Development

ETC participated in a collaborative project with the Catalyst Division of the Energy Research Laboratories (formerly known as CANMET), Perkins Engine, Engine Control Systems and Ortech to conduct Phase 1 of the development of a NOx reduction catalyst for diesel engines. The objective of the first phase of the testing was to conduct a quantitative analysis of the exhaust for regulated and non-regulated emissions with emphasis on polycyclic aromatic hydrocarbon compounds. For this work, ETC designed and fabricated a low-residence-time dilution tunnel for connection directly to the Perkins test engine exhaust manifold. In addition, a computerized sampling system was designed and fabricated for multi-sample multi-component testing. This equipment was taken to the Ortech facility in Mississauga, where the engine was to be tested. The system was setup, calibrated and used to collect samples of volatile organics, carbonyls, regulated emissions, and polycyclic aromatic hydrocarbons. The samples were transferred back to ETC for analysis.

Low-Blend Ethanol Fuels for Small Aircraft Operation

In a joint project with the Transportation Systems Division, ETC setup an 85-Hp light-duty aircraft engine for emissions characterization and operation on low blends of ethanol and aviation fuel. The two-fold objective of this work was to investigate the exhaust emissions from this form of aircraft engine for inventory purposes, while operating on normal fuel, and to assess the potential for operation on low blends of ethanol fuels for future certification. During the initial work in 1995, the engine was connected to a 200-Hp electric engine dynamometer. However, using this methodology it was not possible to operate the engine due to overheating. The engine was then installed in the aircraft chassis with the propellor to provide adequate cooling. Tests were conducted to characterize the exhaust while operating on normal aviation fuel. Low percentages of ethanol were then splash blended with the aviation fuel. As the blend volumes increased, it was necessary to recalibrate the carburetor to compensate for the ethanol. The final test sequences are scheduled in the spring of 1996.

Inspection and Maintenance Dynamometer

A contract was established between Dynotech, a small Canadian company, and Environment Canada to transfer the technology developed by ETC for the fabrication of a computer-controlled electric-motor-powered vehicle emissions chassis dynamometer. The contract stipulated that the technology would be available for the fabrication of one demonstration unit to be completed by the beginning of March 1996. In addition to the demonstration unit, ETC has opened negotiations with Dynotech for a license to construct and sell this technology in both the national and international marketplaces.

5.2.3 Alternative Engines/Vehicles

Diesel-Electric Hybrid 40-Passenger Urban Bus

_General Electric, with the support of a number of Canadian and US companies, including Ontario Bus Industries, developed a hybrid diesel-electric system for an urban bus with an electric motor powering one of two rear axles. A Cummins diesel engine operating at steady-state conditions connected to a generator was used to provide the power for the electric motor. The prototype bus had the engine-generator in a trailer which was pulled by the bus. The final version is designed to have this equipment integrated into the back section of the bus. ETC participated by testing the system for energy efficiency/consumption and exhaust emissions from the diesel-generator hybrid.

Westward Industries

As an extension of a test program conducted in 1993 for Westward Industries to support the California and US certification of a three-wheeled mini delivery vehicle, ETC was requested, in 1995, to conduct a similar program on a new engine configuration. The cost-shared testing was conducted according to the California certification protocols for a motorcycle. All of the test results complied with the certification standards, and Westward is proceeding with the certification process.

Hybrid Electric Vehicles

As part of a joint PERD-funded program with the University of Alberta and the Transportation Systems Division, ETC undertook the evaluation of two electric/gasoline hybrid vehicles designed and fabricated by the students participating in the International Hybrid Vehicle Challenge organized by the Society of Automobile Engineers. The PERD-sponsored evaluation was implemented to demonstrate this vehicle technology under normal in-service conditions in Edmonton.

Both vehicles were parallel-drive systems with small 1.0 L Suzuki gasoline engines serving as the prime movers, with 30-kW electric motors connected in parallel for acceleration and high speed. As a result of the ETC work, several recommendations were provided to the students to reduce the exhaust emissions from the gasoline engine and to improve the performance of the vehicles. The second vehicle won the overall competition and placed first in the exhaust emissions session.

In a second program on hybrid vehicles, ETC collaborated with Concordia University and Transport Canada to undertake an evaluation of a student-designed and -fabricated vehicle (as part of an international student challenge). ETC conducted a similar evaluation to those performed on the University of Alberta vehicles, and then provided recommendations to the project coordinator prior to the vehicle being put into service by the City of Montreal. After 12 months of in-service operation, the vehicle is to be returned to the ETC to repeat the evaluation. This latter work is scheduled for early 96/97.


6.0 SUPPORT TO SPILL RESPONSE

6.1 On- and Off-Site Assistance Summary
6.2 List of Spills/Incidents where Assistance was Provided


6.1 On- and Off-Site Assistance Summary

Specific operational support from ETC during environmental emergencies is identified below:
  • advice on hazardous material properties, behaviour, fate and environmental effects using experience/knowledge and up-to-date manuals and databases;
  • laboratory tests to determine physical, chemical and ecotoxicological characteristics of hazardous materials, and the effectiveness and effects of spill-treating agents;
  • advice and laboratory support regarding the analysis of complex, dirty samples for organic parameters and for a broad range of toxic inorganic elements;
  • assistance in the identification of the potential source(s) of the spill and estimation of the time since the spill;
  • spill-behaviour and spill-movement modelling using the latest-generation models and techniques;
  • advice and training regarding personnel protection at pollution emergencies;
  • advice and direct support regarding state-of-the-art, on-site monitoring of human and environmental hazard levels at pollution emergencies;
  • advice and direct support regarding sample collection at spill sites;
  • advice, on-site support and contract administration of airborne services for the remote sensing of spills;
  • advice and on-site support involving set-up and operation of equipment for sampling pollutants in ambient air;
  • ambient air quality data interpretation and assessment of impacts of pollutants measured;
  • advice on, and evaluation of, spill countermeasures, particularly relating to containment and recovery, treatment and disposal techniques;
  • laboratory bench-scale testing to assist in the selection of chemical-spill cleanup- technologies; and
  • on-site specialized cleanup support at chemical spill and insecure hazardous waste sites through deployment of state-of-the-art prototype mobile water and soil treatment systems.

6.2 List of Spills/Incidents where Assistance was Provided

During the last decade and a half, ETC has provided most of the departmental technical advice, central laboratory, and on-site specialized support during response to pollution emergencies of federal interest. Table 1 identifies the information and advice that was provided by ETC during pollution incidents from April 1, 1994 to March 31, 1996. Recent examples that involved hazard- and contamination-level measurement support on-site include the sulphuric acid spill in Herv� Junction in Qu�bec and the PCB fire in Sydney, Nova Scotia.

Table 1 - List of Spill/Incidents where Assistance was Provided by ETC from April 1, 1994 to March 31, 1996

(*2002-Feb-11: Table data unavailable, Please contact ETC for this information)


7.0 SPILL MEASUREMENT, BEHAVIOUR AND EFFECTS

7.1 Spill Modelling
7.2 Laser Fluorosensor Oil Detection
7.3 Air-Borne Oil-Slick Thickness Sensor
7.4 Chemical Spill Analytical Projects
7.5 Oil Properties and Analysis
7.6 Behaviour of Spilled Oils (BOSS) Project
7.7 Biological Methods Development/Testing of Spilled Substances
7.8 Environmental Fate, Behaviour and Effects of Oil
7.9 Post-Spill Monitoring


7.1 Spill Modelling

The World Oil Spill Model (WOSM) was completed this year, jointly with the Canadian Association of Petroleum Producers, Chevron, Exxon, ASA, Mobil, and the U.S. Army Corp of Engineers. Cut-backs have meant that the operational implementation of the model cannot take place across the Department. ETC provides services, on a full cost-recovery basis, using a variety of spill models. ETC has remained active on committees dealing with the science of modelling, but because of lack of resources, has dropped its own plans for continuing development and operational implementation of improved models.

7.2 Laser Fluorosensor Oil Detection

Laser fluorosensors offer great potential for remote sensing of oil spills, by promising positive discrimination of oil from many interferences, including vegetation and rocks having similar colouration to oil, and wind slicks. Such interferences have caused difficulty in detecting and mapping oil during major spills like the Exxon Valdez.

An older prototype unit, known as the Laser Environmental Fluorosensor, has been installed in the DC-3 aircraft owned by ETC. This unit has been tested over several oil spill and discharge sites. The unit has performed well beyond expectations. Staff members have constructed new electronics for the unit which give map-like output in real-time plus many data analysis tools.

A new fluorosensor is under construction and scheduled for completion in 1997 by Barringer Research and Optec of Toronto. The new unit features scanning capability (a major short-coming with older instruments), a powerful new-generation laser (5 times the power), and an integrated electronic display.

The laser fluorosensor research is jointly funded by Environment Canada, the U.S. Minerals Management Service, the Environmental Innovation Program, Transport Canada, and the United States Coast Guard.

7.3. Airborne Oil-Slick Thickness Sensor

Knowledge of slick thickness is important in order to maximize the effectiveness of oil recovery or treatment operations. A technique has been identified with the potential capability for remotely gauging oil slick thickness. This employs a laser beam to initiate a train of acoustic waves in oil slicks. The frequency of the acoustic waves is a function of slick thickness. The frequency of the acoustic waves is then measured remotely using laser interferometry techniques.

In 1992, a full-scale mock-up of the system was successfully tested in a tank in the laboratory, with waves, up to a distance of 60 metres. In 1993, the mock-up was mounted and tested in an aircraft. The unit functioned on the ground but did not function in flight. The malfunction in flight has been attributed to non co-linearity of the laser beams, and the pickup of extraneous acoustical signals and vibrations by the detector. The mock-up unit is being re-configured to address these problems, using a newly developed detector. In 1996, the new unit will be tested in flight.

The airborne oil-slick thickness sensor research is jointly funded by the U.S. Minerals Management Service, Environment Canada and ESSO Resources Canada.

7.4 Chemical Spill Analytical Projects

ETC continues to develop analytical techniques and provide analytical services to assist spill responders on- and off-site. ETC is equipped with vehicles that carry a range of person-portable and vehicle-portable equipment to ensure rapid response at a site. On-going development of laboratory methodologies is being carried out with the ultimate goal of being able to use the methods on-site. Advanced sampling technologies, such as remote-controlled sampling helicopters, have also been refined and used during the reporting period. Auxiliary support vehicles, including a decontamination unit and command/communication units for supporting crews are also under development. All on-site work is now performed under full cost recovery. In FY 94/95, on-site assessments were performed at about 5 sites, and in FY 95/96 at about 100 sites. The growth of this activity is attributed to both the recognition of ETC’s unique capability in the field and private industry’s limited capability in this area.

ETC maintains, and continues to update reference literature on the properties, fate and effects of over 5000 chemicals and oils. This literature is extremely useful during spill situations.

7.5 Oil Properties and Analysis

Knowledge of oil properties and behaviour is essential for the prediction of environmental fate and effects of oil spills, and for the selection and performance of cleanup and recovery techniques. Not only are there gaps in these data, but some of the older data and measurement techniques are unsound.

New measurement techniques are being developed as well as "total analysis" techniques, which, to date, can quantify over 280 compounds in oil. Methods are being developed to analyse the bulk constituents of oil, especially waxes, resins and asphaltenes. Studies are underway involving the correlation of dispersion, emulsification and other important behavioural processes with the bulk components of oils. ETC is also conducting studies to improve oil analysis for environmental purposes, such as rapid means to measure solubility, and developing new weathering and dispersability procedures to simulate natural processes in the laboratory. The methods have been used for studying the fate and behaviour of spills and for locating unknown spill sources. In the past two fiscal years, over a dozen ‘mystery spills’ were tracked to potential sources.

7.6 Behaviour of Spilled Oils (BOSS) Project

The BOSS project is a major program, co-funded by the U.S. Minerals Management Service, to combine all the findings of the previous joint projects and the literature on spilled-oil behaviour into one source. No literature collection or review of this type exists at the moment. Over 4000 references have been collected and initially reviewed. Completion of the project will result in a major volume combining not only the reviews of literature, but also data tables and unpublished results. This will enable future re-evaluation of processes and use of data for spill behaviour and fate modelling. In the past two years, the oil-in-ice review has been largely completed, with financial assistance from the Environmental Emergency Branch.

7.7 Biological Methods Development/Testing of Spilled Substances

It is important to be able to determine the toxicity of substances which are spilled or likely to be released into the environment. This information affects environmental impact predictions and the selection of cleanup response options. ETC continues to conduct bioassay testing on a variety of chemical and petroleum hydrocarbon substances; however, recent emphasis has been placed more on the development of test procedures, so that there are reproducible and accurate means of measuring toxicity. ETC has been an active partner in efforts to improve the use and acceptability of biological methods and data. To date, fifteen reference procedures have been produced, which now provide Canadian laboratories, program managers and regulators with a well rounded array of options.

Many substances are difficult to test owing to their low solubility or tendency to transform in water. To address one such common substance, a project commenced on the development of a standard method for preparing a water-soluble fraction from petroleum hydrocarbons for aquatic toxicity testing. The project, which has attracted international interest and participation, addresses some of the fundamental and overlooked issues with respect to oil behaviour.

7.8 Environmental Fate, Behaviour and Effects of Oil

In order to select the most appropriate response option for a particular section of oiled shoreline, the operational staff and environmental advisors must make predictions about natural oil removal rates, the effects of the oil on biota and recovery rates. Subsurface intertidal oil contamination remains a significant issue and major factor related to cleanup decisions and long-term effects, yet our knowledge base in this area is very weak.

To address this knowledge gap, ETC is conducting a series of bench-scale studies to investigate subsurface intertidal-zone oil behaviour, i.e., to measure the loading capacity, residual-oil capacity and permeability of sediments of different grain sizes using a variety of different oil types (properties). A second project has been the acquisition, review, selective extraction and consolidation of tens of thousands of records of oil-on-shoreline data collected from monitoring programs in Prince William Sound conducted during US Government and EXXON surveys. A third initiative has been the development of the only known comprehensive model to predict oil removal rates from marine shorelines.

7.9 Post-Spill Monitoring

Post-spill monitoring may be conducted to evaluate the cleanup actions/decisions which were taken, and to verify and refine predictions of longer-term oil fate and behaviour, effects and rates of biological recovery. Two surveys were conducted during the review period which focused on the natural removal rates of oil on shorelines. In 1995, a systematic regional survey was conducted of four old pipeline spills in western Canada. One of the spills is over 28 years old. Some of the treatment technologies on this particular spill did not work well and the plots where these were used remain unvegetated. These results continue to advance our understanding of the long-term behaviour of oil in these environments and the best countermeasures for such spills.


8.0 SPILL COUNTERMEASURES R&D

8.1 In Situ Burning and the Newfoundland Offshore Burn Experiment (NOBE)

8.2 Chemical Spill-Treating Agents
8.3 Countermeasures Effects Evaluations
8.4 Shoreline Cleanup Techniques and Response Evaluation
8.5 Bioremediation
8.6 Sorbent Evaluation
8.7 Mechanical Containment and Recovery Equipment Evaluation
8.8 Standards Development


8.1 In Situ Burning and The Newfoundland Offshore Burn Experiment (NOBE)

Several recent large accidental oil spills have re-confirmed that shoreline oil contamination causes extensive environmental damage and results in very high cleanup costs. Analysis of the Exxon Valdez oil spill indicated that perhaps more than half of the spilled oil could have been burned in situ without igniting the oil remaining in the vessel, thereby significantly reducing shoreline contamination.

Intensive laboratory and tank testing on the in situ combustion of oil indicated that the nature and concentrations of atmospheric emissions from in situ burning of oil offshore will sometimes be preferable when weighed against the environmental damage and cleanup costs of near-shore and shoreline contamination.

Based on this knowledge, a controlled experimental release and burning of oil under realistic full-scale field conditions inside a fire-resistant boom was planned. The experiment was designed to allow confirmation of the chemical species associated with the burning of oil on the open ocean (particularly smoke and gaseous emissions). It was also planned to allow the verification of theoretical models developed, tank tests undertaken to predict the content and trajectories of smoke plumes and contamination levels in the water column. It was considered essential to provide the necessary information for regulatory agencies to consider pre-approval for large-scale burns of spills - an essential element in making effective use of burning in a field situation. An equally important benefit involves the development of operational response protocols that will guide oil industry, spill cooperatives and government regulatory personnel in the safe and effective application of burning in future spills.

Consequently, a consortium of over 25 agencies from Canada and the United States planned and conducted an experimental release and in situ burn of oil off St. John's, Newfoundland on August 12, 1993 - the Newfoundland Offshore Burn Experiment (NOBE). The burn involved two oil discharges of about 50 tons each into a fireproof boom. Each burn lasted over an hour and was monitored for chemical and physical parameters. Over 200 sensors and samplers were employed and these provided data on over 2000 parameters and substances. The operation was extensive, involving over 20 vessels, seven aircraft and 230 people at-sea.

The extensive data set contributed to our knowledge of in situ burning. The analytical data, to date, clearly show that the emissions from this in situ oil fire were less than expected. All compounds and parameters measured were below health concern levels beyond about 150 metres from the fire and very few chemicals were detected beyond 500 metres. Pollutant levels were found to be lower than in previous tank tests. The detailed reasons for this are not fully understood, but the offshore test appears to have involved more efficient combustion.

The concentration of PAHs was found to be lower in the soot than in the discharged oil, since they were largely consumed by the fire. Particles in the air were measured by several means and found to be of concern at sea level only up to 150 metres downwind. Particulate matter may not be a concern past this distance, except in the smoke plume itself. Combustion gases, including carbon dioxide, sulphur dioxide and carbon monoxide, did not reach levels of concern. Volatile organic compounds (VOCs) were detected in high concentration close to the fire, but were less than VOC levels emitted from the non-burning slick. Over 50 compounds were quantified, several at levels of concern near the sea surface up to 150 metres downwind.

Water under the burns was analysed and no compounds of concern could be found at the detection level of the methods employed. Toxicity tests performed on marine organisms using this water did not show any acute or sublethal adverse effects, beyond those already associated with unburned oil. The burn residue was analysed for the same compounds as the discharged oil and the air samples. PAHs were at a lower concentration in the residue than in the starting oil. Overall indications from these burn trials are that emissions from in situ burning are relatively low in comparison to many other sources of emissions, and result in concentrations of air contaminants that are acceptable beyond 500 metres downwind.

Although additional scientific and operational work is still needed, the NOBE results confirm that in situ combustion of oil slicks concentrated by fire-resistant booms, is indeed a practical oil spill response method. Another series of smaller burns were conducted in 1994 in Mobile, Alabama. Analysis continues on this series of tests.

8.2 Chemical Spill-Treating Agents

Since treatment of oil or chemical spills involves the application of additional chemicals to the environment, it is essential that adequate information is available about their toxicity and effectiveness. ETC is developing and implementing tests in these regards.

Performance tests will ultimately be developed for twelve classes of chemical spill-treating agents. So far, tests have been developed for dispersants, solidifiers and surface-washing agents. Over 250 agents from these three classes have been tested in recent years. Preliminary tests have also been developed for emulsions breakers, recovery enhancers and emulsion preventers. Work is continuing to finalize these latter tests and to test new agents.

The chemistry (especially stability over periods approaching days) and physics (especially dispersant particle size) of dispersants are being studied. In addition, work will continue on the development of new dispersants. Some of the prototype formulations offer potential to disperse heavy oils, including Bunker C.

This work is jointly funded by Environment Canada and the U.S. Minerals Management Service.

8.3 Countermeasures Effects Evaluations

To assess the relative benefits of different cleanup techniques, it is imperative to know the environmental effects and to conduct environmental evaluations of various countermeasures and response practices. Although the majority of effort has been directed toward bioremediation and shoreline cleanup, some work has also been conducted on chemical and in situ combustion techniques.

ETC continued its program of testing oil-spill dispersants and other spill treating agents in order to determine toxicity. At the EPS Atlantic Region Laboratory in Dartmouth, N.S., rainbow trout acute lethality testing was completed on about 30 agents. Microtox testing of new agents continues at ETC. More comprehensive lethal and sublethal bioassays were conducted under contract on a limited number of products at several other commercial test facilities.

The environmental effects of in situ burning of oil-on-water were addressed in a study designed to measure aquatic toxicity associated with burned and unburned crude oil in the water column. Chemical analysis and five different types of toxicity tests were performed on laboratory-generated burn samples and on full-scale field burn samples. Results generally indicate that lethal and sublethal toxicity were extremely low and that in situ burning did not adversely affect the underlying water column, beyond those effects already associated with unburned oil.

8.4 Shoreline Cleanup Techniques and Response Evaluation

Decisions on whether or not to clean an oiled shoreline and how best to do it, require information on the effectiveness of various response options to determine and minimize environmental risk and to optimize performance. ETC, together with the U.S. Minerals Management Service and other supporters, have been investigating various means to mount field-scale comparative evaluation studies of cleanup techniques. These efforts continue and are expected to lead to field projects in the next review period.

In another initiative, the application of environmental knowledge and criteria is being used to improve spill-response approaches. Real-time data on oiling conditions at a shoreline are needed to appreciate the nature and scale of the oiling problem. They are also needed to facilitate spill-response planning and decision-making, including the assessment of the need for cleanup actions, the selection of the most appropriate technique, the determination of priorities for cleanup, and the determination of the endpoint of cleanup activities. Consistent data sets (observations and measurements) on shoreline oiling conditions are essential for each spill in order to both compare the data between different sites or observers, and to compare the data against existing benchmarks or criteria which have been developed in order to rate the nature or severity of the oiling. ETC has developed and promoted standardized methods for documentation and description of oiled shorelines. The SCAT (Shoreline Cleanup Assessment Team) concept and associated terminology has now been endorsed by all major North American spill response agencies. Its usage is now required by many government agencies and corporations.

Studies of washing techniques are continuing at the pilot-scale. A larger-scale test has been initiated at Bamfield, on Vancouver Island, B.C.

8.5 Bioremediation

The period following the Exxon Valdez incident saw a resurgence of interest in oil spill bioremediation techniques, including the appearance of a large number of bioremediation products on the market. In order to provide guidance to response personnel on commercial product performance and on the role of bioremediation in cleanup, the ETC initiated several projects to address oil biodegradation issues.

Draft "Guidelines for Assessing the Efficacy and Toxicity of Oil Spill Bioremediation Agents" provide standard laboratory methods for performing an initial 'screening-level' evaluation of products that are intended for use in treating oil spills in marine and freshwater environments. Testing has been performed on a range of commercially available products as a part of the validation of the methods.

A second continuing project is to develop and assess the feasibility of a standard laboratory protocol to determine the relative biodegradability potential of crude oils, under simulated warm freshwater and cold marine conditions. This information will be useful for oil removal predictions, since each oil has varying degrees of susceptibility to biodegradation processes.

In conjunction with the above work, ETC has developed standardized freshwater and marine oil-degrading bacterial consortia. These will provide benchmarks for laboratory studies on oil biodegradation and greatly improve the reproducibility of test results. Similarly, investigations are underway to measure chemically if and how much biodegradation has occurred.

8.6 Sorbent Evaluation

ETC led a project to develop an improved performance standard for the testing of oil spill sorbents. A Canadian General Standards Board testing protocol was developed which targets performance parameters for sorbents used to combat oil spills. Additional work was performed in conjunction with organizations in the United States to ensure that compatible testing protocols were developed in the USA. Results are being tabulated in a database which will eventually be made available as a public resource on the Internet.

Development was started on a similar protocol targeting sorbents used for chemical spills. Sorbent performance and chemical compatibility are the initial parameters which are being investigated.

8.7 Mechanical Containment and Recovery Equipment Evaluation

Recently, ETC has worked jointly with a Norwegian research institute, SINTEF NHL, on three oil spill R&D projects. This is part of continuing international cooperation on marine oil spill research between Canada, Norway, the United States and other European nations.

The objective of the initial study was to investigate the feasibility of using oil demulsifying agents during oil spill recovery operations. In typical recovery operations, the majority of the oily product recovered is in the form of a high-water-content water-in-oil emulsion (60% to 80% water). Demulsifiers can effectively be used to reduce the volume of water trapped in the oil and hence, reduce the storage volume required.

Test variables being investigated included demulsifier dosage rate and mixing energy required for an efficient demulsification process to take place. Tests were conducted at ETC's Oil Engineering Test Facility during the two last weeks of November 1995. The project was performed on a cost-recovery basis and was funded by the Norwegian State Pollution Control Authority (SFT; analogous to Environment Canada) and the United States Marine Spill Response Corporation (MSRC).

The second study consisted of a series of tests with a weir skimmer to provide experimental data for a theoretical model being developed. The model will be used to predict recovery performance (e.g., recovery rates and recovery efficiencies) of this particular skimming principle in various operating conditions. Carefully controlled tests were performed, while varying parameters such as oil thickness, oil properties, scale, and flow rate. The model being developed will assist responders with planning contingency strategies, selecting appropriate skimmer operating settings, and predicting recovery rates and efficiencies for expected conditions. This study was also performed on a cost-recovery basis and was funded by SFT.

Lastly, a technical working group has met to discuss the current state-of-the-art technologies for recovery of oil spills in ice-infested waters. This study will review the advantages and limitations of the available technologies and proceed with detailed engineering analyses to improve current techniques.

8.8 Standards Development

ETC, since 1991, has been involved in a program of standards development for oil-spill cleanup in partnership with the U.S. Coast Guard Oil Pollution Act, 1990 (OPA 90) Office and others. The standards in the area of mechanical containment and recovery are being developed through the applicable American Society for Testing and Materials (ASTM) F-20 sub-committee to ensure compatible standards for North America, at least. ETC is also participating in other areas such as sorbents, remote sensing, dispersants, communications, and in situ burning. Very good progress has been achieved in all areas, with twenty-five standards produced since the start of the accelerated program. Eight more are under development.


9.0 INTERNATIONAL TRANSFER OF CANADIAN TECHNOLOGY

9.1 Ukraine
9.2 Latvia
9.3 China and Hong Kong
9.4 Mexico
9.5 Sweden


9.1. Ukraine

9.1.1 Rationale and Goal
9.1.2 Training Program
9.1.3 Preliminary Environmental Assessment of Former ICBM Site
9.1.4 Laboratory Accreditation


9.1.1 Rationale and Goal

Canada is supporting the denuclearization of Ukraine and Ukrainian accession to the nuclear Non-Proliferation Treaty (NPT). As part of the process, ETC, in conjunction with their private-sector and Ukrainian partners, are helping to transfer Canadian techniques and equipment for environmental assessment and remediation of the chemical contamination at Inter-Continental Ballistic Missile (ICBM) sites and associated facilities. It is known, from past experience with former Soviet military sites, that severe environmental clean-up problems can be anticipated, which involve petroleum products, polychlorinated biphenyls, pesticides, heavy metals and missile fuels and their oxidants. Hydrazine with nitric acid was commonly used to propel SS-19 missiles, which formed the bulk of Ukraine’s nuclear arsenal. Although Canada did not have ballistic missiles, much of the pollution at these locations is similar to that found at former Canadian bases.

The goal of the Environmental Assessment and Remediation Project (EARP) is to give Ukraine the independent capability to undertake environmental assessment and remediation of former ICBM sites, including the infrastructure and facilities surrounding the actual ICBM sites. The goal will be achieved by:
  • providing Ukraine with Canadian techniques and equipment for continuing environmental assessment and remediation, by training and equipping a cadre of engineers, chemists and technologists; and
  • giving Ukraine the capability to establish its own training programs in the future by using the small cadre of Canadian-trained experts to train other Ukrainians in Canadian procedures and technology.

The EARP is structured as a Canadian public and private joint project to be carried out by ETC and private-sector partners Fenco MacLaren Inc (FMI) and Gartner Lee International Inc. (GLII), with funding support by the Canadian International Development Agency (CIDA). It proposes to introduce Canadian techniques and equipment into Ukraine, by training Ukrainian personnel in Canada and by assisting the Ukrainians to carry out small environmental assessment and remediation demonstrations at one or two sites.

9.1.2 Training Program

Under the EARP, 18 to 24 Ukrainians, consisting of engineers and scientists, will be trained in Canada for a 10-to-12 month period. The first group of nine trainees arrived in June 1995, while the second group of twelve to fifteen trainees will arrive in September 1996. The trainees for the EARP are primarily from the Ukrainian Ministry of Defence, since this is expected to be the group most closely associated with the actual remediation of the sites. However, representatives from the Ukrainian Academy of Science and the Ukrainian Ministry of Environmental Protection are also included.

The formal or “classroom” training of the Ukrainian personnel takes place primarily at the facilities of the Canadian private-sector partners located in Toronto and at ETC. The informal or “hands-on” training consists of visits and job shadowing, which means that the trainees will have an opportunity to visit and work with staff on active projects in environmental assessment and remediation. Approximately 60-70% of their training period is with ETC while 30-40% is with the private-sector partners.

The formal training is divided into two parts: (1) learning how to conduct environmental assessment and remediation activities/projects; and (2) learning the philosophy of doing business in Canada.

The first part covers training in: Workplace Hazardous Materials Information; Laboratory Safety; Steps for Conducting Environmental Site Assessment; Field and Laboratory Analytical Methods; Personal Protective Equipment and Clothing; Environmental Philosophy; Environmental Regulations and Criteria; Identification, Classification and Assessment of Contaminated Sites; Geophysical Investigation Techniques; Drilling; Installing Monitoring Wells; Sample Collection, Logging and Analysis; Quality Assurance/Quality Control; Risk Assessment; Steps for Choosing and Implementing Remedial Technologies; Health and Safety; Public Involvement and Community Relations; Site Closure; and Long-term Monitoring.

The second part covers training in: English; computers; finances; accountability; project management; and time management in the Canadian workplace.

The informal training comprises: tours of companies; tours of centres; tours of Universities; demonstration of laboratory analytical instruments; workshops; evaluation of environmental assessment and remediation proposals; participation in Canadian and Ukrainian environmental assessment and remediation jobs; analysis of soil and water samples; development of analytical and remediation methods specific to Ukrainian environmental problems; job shadowing; and on-going self-directed study and practice of skills.

9.1.3 Environmental Site Assessment at Former Missile Site

A preliminary environmental site assessment demonstration at a former ICBM site (No. 38), near the city of Khmmelnitsky, was conducted by all partners in September 1995. The purpose of the demonstration was three-fold and achieved: (1) to acquaint the Team with the history, layout and environmental conditions of a typical Ukrainian launch site and command post; (2) to provide an opportunity for the Ukrainians to obtain hands-on assessment training and experience on their own territory; and (3) to familiarize the Team with the current infrastructure in Ukraine for undertaking environmental assessment and remediation activities. Interestingly, the former ICBM site was determined to be relatively clean; although there was some minor gasoline, diesel and fuel oil impact around the support buildings.

9.1.4 Laboratory Accreditation

The International Environmental Management Initiative funded a team visit by representatives from the Environmental Sciences Centre, Winnipeg, the Canadian Association of Environmental Analytical Laboratories and ETC to the Ukrainian Ministry of Environmental Protection to discuss the development of a system for laboratory accreditation.

9.2 Latvia

9.2.1 Rationale and Goal
9.2.2 Training Program
9.2.3 Environmental Assessment of Former Missile Sites


9.2.1 Rationale and goal

Following the collapse of the Soviet Union, Latvia was left with just over 400 former Soviet military installations, including bases, in deplorable conditions. The environment surrounding numerous army and air bases throughout the country was contaminated by the disposal of missile fuels (e.g., SAMIN), petroleum products, kerosene, polychlorinated biphenyls, pesticides, acids and other contaminants. Latvia has sought Canada’s cooperation and technical assistance. Latvia cannot effectively manage this contamination, since it does not have the skills or equipment necessary to do so.

The objectives of the Latvian Environmental Centre of Excellence Project (ECEP) are to:
  • establish an Environmental Technology Centre of Excellence at Riga Technical University;
  • provide Latvia with a small cadre of engineers trained in Canadian techniques and equipment for environmental site assessment and remediation;
  • give Latvia the capability to establish its own training programs in the future by using the small cadre of Canadian trained experts to train other Latvians in Canadian procedures and technology; and
  • carry out an environmental site assessment and remediation demonstration at former missiles sites in Latvia.

The ECEP is structured as a Canadian-Latvian public and private joint project to be carried out by ETC and GLII with funding support from CIDA and the Latvian community in Canada. It proposes to introduce Canadian techniques and equipment into Latvia by training Latvian personnel in Canada and by assisting the Latvians to carry out a small environmental assessment and remediation demonstration project at the former Tasi and Barta missile bases. Eight Latvians from RTU will be trained under this project.

9.2.2 Training Program

Training for the Latvians began in June 1994 and will end in 1996. The program is similar to that described for the Ukrainians; however, the emphasis is on the establishment of the Centre for Environmental Excellence in Riga, Latvia. The site assessment demonstration took place in August 1995, and the site remediation demonstration is planned for August 1996.

9.2.3 Environmental Site Assessment of Former Missile Sites

An environmental site assessment demonstration at former missile sites (Barta, Tasi) near the city of Liepaja was conducted by all partners in August 1995. The purpose of the demonstration was four-fold and achieved: (1) to acquaint the Team with the history, layout and environmental conditions of a typical Latvian missile site; (2) to provide an opportunity for the Latvians to obtain hands-on assessment training and experience on their own territory; (3) to familiarize the Team with the current infrastructure in Latvia for undertaking environmental assessment and remediation activities; and (4) to establish the Latvian Centre for Environmental Excellence. The demonstration provided an opportunity to delineate severe spills of SAMIN missile fuel (containing xylidine and diethyl- and triethyl amine) and nitric acid at the former missile site in Barta.

9.3 China and Hong Kong

Following a previous visit by representatives from the Academia Sinica’s Institute of Environmental Science and the Hong Kong Productivity Council, ETC staff visited China and Hong Kong in April 1994 to present lectures on analytical chemistry and laboratory accreditation. Laboratories visited included the Hong Kong Productivity Council, the Hong Kong Laboratory of the Government Chemist, the Institute of Environmental Science and the Chinese National Environmental Protection Agency, the Chinese National Environmental Monitoring Agency, all in Beijing, and the Shanghai Academy of Environmental Science. These visits were funded by the International Partnership Progam.

These visits have led to further exchanges as a representative of the Hong Kong Laboratory of the Government Chemist came to ETC to study the analysis of air toxics. In addition, four members of the Chinese National Environmental Monitoring Agency spent six months working at ETC to study various analytical techniques. This project was financed by the World Bank with additional expenses paid by the International Partnership Program.

In 1994 and 1995, ETC staff visited China to present lectures on analytical chemistry and oil spills at the following laboratories: the University of Beijing, the University of Nanjing, the Petroleum University of Beijing, Beijing Technical University, the Petroleum University of Quanzhou, the Kunming Environmental Institute, the Chinese National Environmental Protection Agency, the Chinese Department of Oceans in Beijing, the Yunnan Department of Environment, the Quanzhou Department of Environment and the Shanghai Academy of Environmental Science. These visits were funded by various government bodies in China.

These visits have led to further exchanges. In addition, one member of the Chinese National Environmental Monitoring Agency spent six months working at ETC to study various oil analytical techniques. This project was financed by the World Bank with additional expenses paid for by the International Partnership Program. The International Partnership Program also paid for the visit of a professor from the Petroleum University of Beijing, who spent six months at ETC conducting research on surfactants for petroleum spill applications.

In 1995, the United Nations Devlopment Progam (UNDP) funded the visit of ETC staff to Dali in Yunnan province where they studied non-point pollution and spills into Lake Erhai. The three-week project culminated in an 80-page report which was widely circulated in China. As a result of this joint work, two Chinese scientists will be sent to ETC to study methodology in environmental assessment and oil spills in 1996.

9.4 Mexico

The International Environmental Management Initiative funded a seminar on laboratory accreditation in Mexico City at the Comiscion National Aqua. The Canadian team consisted of managers of public- and private-sector laboratories representing the International Association of Environmental Testing Laboratories, CAEAL and ETC.

ETC hosted two scientists from the Instituto Nacional de Ecologia of Mexico to learn more about Canada’s system of air toxics monitoring and hazardous waste management. This exchange was funded by the International Partnership Progam.

These two projects were part of the Mexico-Canada Agreement on Environmental Cooperation.

An increase in the interest in environmental measurement in the context of the North America Free Trade Agreement (NAFTA) resulted in the formation of the North American Environmental Quality Assurance Plan. This plan is supported by many environmental agencies in the three NAFTA countries. A representative from ETC assisted in the planning meetings held in Queretaro, Mexico, during November, 1994, and in Silver Springs, Maryland, May, 1995.

9.5 Sweden

A post doctoral fellow from the Department of Water and Environmental Studies, Link�ping University of Sweden spent 15 months studying capillary electrophoresis (CE) in humic substances characterization. This fellowship was funded by the Werner-Gren Foundation and Linkoping University of Sweden. An aquatic fulvic acid was chosen as a representative humic substance. Two approaches were undertaken. In the first, the complexation capability of fulvic acid was studied, by using CE for the determination of free metal cations (Sr2+, Pb2+, Cu2+, Hg2+ and Al3+) studied. The second approach examined the electrophoretic behavior of the fulvic acid and its complexes with Hg 2+ and Fe3+.


10.0 TECHNOLOGIES FOR DECONTAMINATING WATER

10.1 Removal of Heavy Metals using Adsorption and Microfiltration
10.2 Electrolytic Reduction of Nitrosamines
10.3 Evaluation of Lab-Scale Technologies for Treating Xylidine- Contaminated Water
10.4 Recovery of Ammonia from Waste Streams


10.1 Removal of Heavy Metals using Adsorption or Polymeric Binding and Microfiltration

10.1.1 Arsenic
10.1.2 Lead
10.1.3 Chromium
10.1.4 Selenium


ETC and Zenon Environmental Inc. have developed a technology for the removal of heavy metals from aqueous streams such as ground water, mining effluents, and other industrial waste waters. The treatment process incorporates the adsorption of the heavy metal onto finely dispersed activated alumina followed by microfiltration.

A second technology being investigated involves the use of selective polymeric binding followed by microfiltration. The selective nature of specific polymers is being studied, as well as the interference of common competing ions and other operating parameters.

10.1.1 Arsenic

Contamination of the environment with arsenic is a common problem resulting from human activities such as mining, combustion of fossil fuels and agriculture. The mining industry is currently in need of techniques to reach the arsenic discharge limits set by the Canadian government. In collaboration with private-sector partners, ETC has developed two methods for the removal of arsenic from aqueous solutions using innovative systems.

The adsorption / microfiltration technology, which has been patented by the Crown in Canada and the United States, removes arsenic to far below environmental limits within a short period of time. Pilot-scale demonstrations of the treatment process are scheduled to take place in the summer of 1996.

In the second project, a method using selective polymeric binding and membrane separation has been investigated. This process involves the binding of arsenic with a water-soluble polymer, followed by membrane separation. The membrane separation is used to retain the arsenic complex formed during the binding phase between the arsenic and the ion exchanger. During this study, the main problem of the lack of selectivity of conventional ion exchange methods was investigated. This new process allows the effluent to reach levels below the environmental discharge limit of 50 ppb set by the Canadian government. Salinity, the type of polymer, polymer concentration, initial contaminant concentration, and the pH of the solution were studied for their effect on arsenic removal. Experimental results were encouraging, and a field trial is currently being planned in partnership with the private-sector to investigate the potential of this new system in the mining industry.

10.1.2 Lead

A number of further studies were performed to determine the effectiveness of using activated alumina in conjunction with microfiltration to treat lead-contaminated soils. Research concentrated on lead-contaminated soil fines, since this was the main area of operational difficulty. One project involved the removal of lead from highly contaminated soil sampled from a smelting operation site. Two salts, one monovalent (NaCl) and one divalent (MgCl2), were used in experiments to determine their effect on lead removal from soil fines using the chelating agent ethylene diamine tetracetate (EDTA). Tests were first conducted to determine the best pH for the experiments, then the effect of salts and their concentrations on lead removal was studied.

10.1.3 Chromium

The same method used for the arsenic work is now being applied for the removal of chromium from water. Preliminary results shows promise. Using the system developed during the arsenic work, chromium removal exceeding 99.9% has also been achieved from a 30 ppm Cr solution. Additional studies are being performed with different polymers, and the factors which have the largest influence on the extraction are being determined.

10.1.4 Selenium

Selenium-contaminated groundwater and process wastewater have captured growing interest. ETC began studying these problems and is adapting two existing technologies.

The first project involves the application of a new process to remove selenium effectively from water. The process involves the binding of the contaminant by a specific complexing agent followed by membrane separation. This process has been proven efficient for the removal of arsenic and chromium from water. At the present time, the removal of selenium from water is being investigated at the laboratory scale using different binding agents, forms of selenium, polymers and contaminant concentrations. Investigations are been carried out to determine the influence these factors have on the removal of selenium from water.

The second project examines the feasibility of effective selenium adsorption onto activated alumina, the effect of pH on the adsorption process, and the optium pH range for the process. Contact times for Se(VI) and Se(IV) are also being studied. Screening of commercially available activated alumina for determining their suitability is also underway. Pore size distributions and particle size, effect of initial concentration, determination of competing ion effects (sulphate ions), as well as the effect of salinity on the selenium removal process are being explored.

10.2 Electrolytic Reduction of Nitrosamines

Bench-scale studies have been carried out to evaluate the feasibility of electrolytic reduction for the destruction of N-nitrosodimethylamine in water. This work has been done in collaboration with the Department of Chemical Engineering of McGill University and the Electrochemical Science and Technology Centre of the University of Ottawa.

10.3 Evaluation of Lab-Scale Technologies for Treating Xylidine-Contaminated Water

Latvian researchers, in conjunction with their Canadian colleagues, commenced laboratory-scale studies in the fall of 1995 to determine the optimum treatment train for remediating missile sites contaminated with SAMIN (a xylidine-based fuel). The technologies tested for the recovery of xylidine in a concentrated form and the remediation of xylidine-contaminated water were chemical precipitation, steam stripping and advanced oxidation. The effectiveness of steam stripping and chemical precipitation in concentrating xylidine from dilute aqueous solutions for subsequent recovery was investigated, along with the effectiveness of advanced oxidation for the destruction of dilute aqueous xylidine solutions. The pilot-scale water treatment train is currently being designed and constructed, and will be used in August 1996 during a remediation demonstration at a former missile site in Latvia.

10.4 Recovery of Ammonia from Waste Streams

Bench-scale treatability tests were performed to compare different techniques for the removal of ammonia from a mixed waste stream containing both organic and inorganic contaminants in high concentrations as part of the $1-million Challenge from Monsanto. Chemical treatment as a main step of the recovery, followed by advanced oxidation, was found to be the most effective approach by ETC; although was not considered to be the best by Monsanto.


11.0 TECHNOLOGIES FOR DECONTAMINATING SOIL

11.1 Extraction of Heavy Metals using a Membrane-Assisted Process
11.2 Evaluation of Lab-Scale Technologies for Treating Xylidine- Contaminated Soil
11.3 Evaluation of Technologies for Treating and/or Disposing of Antifreeze
11.4 Assistance in Soil Bioremediation Studies at CFB Trenton


11.1 Extraction of Heavy Metals Using a Membrane-Assisted Process

Bench-scale studies have been carried out to evaluate the effectiveness of incorporating membrane filtration with a soil leaching process. McGill and Carleton Universities were ETC’s partners in this work. Test results revealed that this hybrid process demonstrates a higher efficiency than the conventional technology and generates cleaner soil in a shorter time.

11.2 Evaluation of Lab-Scale Technologies for Treating Xylidine-Contaminated Soil

Latvian researchers, in conjunction with their Canadian colleagues, commenced laboratory-scale studies in the fall of 1995 to determine the optimum treatment train for remediating missile sites contaminated with SAMIN (a xylidine-based fuel). The technologies tested for the remediation of xylidine-contaminated soil were low-temperature thermal desorption, soil washing and solvent extraction. The optimum operating parameters and effectiveness of each technology were determined along with their economics and complexity. The pilot-scale soil treatment train is currently being designed and constructed, and will be used in August 1996 during a remediation demonstration at a former missile site in Latvia.

11.3 Evaluation of Technologies for Treating and/or Disposing of Antifreeze

A literature study was performed, on behalf of the Department of National Defence, to investigate three areas related to the use of ethylene glycol as an antifreeze in vehicles and hydronic heating systems. Primary areas of interest were the environmental effects of a spill of ethylene glycol, possible alternative antifreeze solutions, and technologies currently available which could effectively deal with treating and/or disposing of used ethylene glycol.

11.4 Assistance in Soil Bioremediation Studies at CFB Trenton

The Department of National Defence (DND) conducted a field-scale study to compare and analyse the effectiveness of several bioremediation processes at a fire fighter training area at the Canadian Forces Base (CFB) in Trenton which had been contaminated with many different petroleum products over its service life. In the fall of 1995, the soil from the site to be utilized for this project was excavated, screened, homogenized and formed into windrows. The bioremediation processes evaluated were a white rot fungus system, several compost/fertilizer systems, four commercial systems and land farming. The windrows were monitored weekly for temperature, O2, hydrocarbons, CO2, and moisture. Soil samples were taken biweekly for analysis. ETC assisted DND with the windrow monitoring, soil sampling, and performed the soil analysis. Parameters analysed include pH, mineral oil & grease (MOG), purgeable hydrocarbons, total petroleum hydrocarbons (TPHs), PAHs and PCBs.


12.0 CO-ORDINATION OF SCIENCE AND TECHNOLOGY

12.1 Good Laboratory Practice
12.2 Program on Energy Research and Development (PERD)
12.3 Laboratory Managers’ Committee
12.4 Biological Method Development and Application


12.1 Good Laboratory Practice

The Good Laboratory Practice (GLP) Compliance Monitoring Unit is charged with the responsibility of developing a GLP program in support of the New Substances Notification Regulations of CEPA. At present, this program is proceeding on an unofficial basis, pending the development of an official program, since there is a present requirement for the use of GLP in the new substances notification process, which entered into force in 1994.

During the past two years, the GLP Compliance Monitoring Unit has been active in a number of areas. Several Canadian laboratories have agreed to undertake the upgrading of their facilities to GLP status so that they can perform testing in support of Canadian and overseas manufacturers and importers of new substances for the New Substances Notification Regulations of CEPA. The first three of these laboratories were inspected in 1995, and at least three more are expected to be ready for inspection in 1996.

The Unit has represented Canada on the OECD GLP Panel for the past few years, and has assisted in the development of two new OECD advisory/consensus documents and a questionnaire which has been employed to increase the collective understanding of compliance monitoring programs in all OECD Member countries. Members of the Unit, as well as other federal government employees, have also participated in an OECD GLP inspector training course and in training associated with the recently-formed Canadian chapter of the International Association of Quality Assurance.

Unit members have also served as inspectors for CAEAL and have assisted in preparing an Appendix on GLP requirements for the new Canadian Standards Association for Environmental Analytical Laboratories.

Presentations on this emerging Canadian program have been given by Unit members at OECD meetings in Paris and in Mexico, at a private-sector GLP workshop in Toronto, and at meetings of the International Society of Quality Assurance in Canada and the United States. A number of presentations have also been made to various groups and managers within the department.

During 1995, the Unit provided information and support to the newly-formed Pest Management Regulatory Agency, which is planning to introduce a GLP requirement for pesticide registration.

Another of the Unit’s activities has been preliminary negotiation of international agreements which mutually recognize the equivalence of GLP compliance monitoring programs, thus paving the way for the mutual recognition of testing data on new substances - a cornerstone of the OECD Chemicals Program - which leads to decreasing regulatory trade barriers and to a reduction in the international cost associated with health and safety testing of new substances. It is expected that agreements may be reached with the European Union and the United States Food and Drug Administration during 1996; several other potential agreements are at the preliminary discussion stage.

Late in 1995, the Unit participated in an OECD Expert Group meeting mandated to begin a revision of the OECD Principles of Good Laboratory Practice. Work on this project is expected to continue for the next two years, and will hopefully result in greater harmonization of GLP programs all over the world. This activity will go hand-in-hand with the development of Canada’s official GLP compliance monitoring program, which will include the preparation of options and briefing papers for senior departmental officials and the initiation of formal consultations on program development.

12.2 Program on Energy Research and Development (PERD)

The Program on Energy Research and Development (PERD) is designed to support research and development in five broad research areas of interest to Environment Canada. These are: Energy Efficiency; Coal; Renewable Energy; Alternative Transportation Fuels; and Oil, Gas and Electricity. Funds for this program (about $9M for this two-year period) are provided by Natural Resources Canada, through the Office of Energy Research and Development. Some 50 projects of interest to the department have been supported by PERD during the past two years. In addition, the department has been provided with 8 full-time equivalent person-years to support these activities. Recent projects have dealt with such interests as: process improvements at co-generation plants for steam and electricity; bioremediation and bioreclamation of contaminated soils at oil and gas well sites; purification of water employed in enhanced oil well drilling techniques so that it can be recycled; and development of improved gas flaring methodology at petrochemical refineries. Recent R&D projects carried out at ETC have also received funding from PERD, such as microwave-assisted solvent extraction techniques, work on alternative transportation fuels, and reclamation of beaches contaminated by crude oil spills.

The administration of these funds for ECS and EPS is performed by the GLP Compliance Monitoring Unit. Each year, this involves activities such as: notifying departmental researchers of areas in which funding is available; soliciting initial proposals, or “Letters of Interest”; evaluating initial proposals; requesting full proposals; evaluating proposals; recommending proposals for funding; and monitoring project progress and finances. This work is carried out in cooperation with task group leaders, departmental PERD coordinators, project managers, and financial support staff.

The PERD program is presently undergoing significant structural and financial changes as a result of the government-wide Program Review, and the next two years will require considerable effort to adjust to these changes.

12.3 Laboratory Managers’ Committee

ETC is represented on the EC Laboratory Managers’ Committee (LMC) by the Assistant Director and the Chief, A&MD, the latter acting as Chair for the last three years. The role of the LMC is to coordinate activities concerning laboratories. Typical of these is the direction of laboratory work to the most suitable laboratory. For example, A&MD has received samples for analysis of Ozone Depleting substances from Atlantic Region, the analysis of legal samples for PAH analysis from Pacific &Yukon Region and the analysis of samples for air toxics from Quebec Region. Regular items are the coordination of QA/QC and health and safety activities. The LMC manages projects such as the establishment of a database for analytical methods, the establishment of Standard Guidelines & Documents for Contract Analytical Services, and the development of Canadian Shellfish Contaminants Monitoring QA\QC Analytical Guidelines. The LMC also works collaboratively with such groups as Canadian Association of Environmental Analytical Laboratories, the International Association of Environmental Testing Laboratories, the USEPA, the Intergovernmental Committee for Analytical Methods, and the Inter-Government Aquatic Toxicological Work Group.

Collectively, the group provides advice to various departmental programs such as the CEPA Priority Substance Lists 1 & 2, the Accelerated Reduction & Elimination of Toxics, Environmental Stewardship, Environmental Choice, Toxic Substances Management Policy, the revision of CEPA, as well as on the development of various regulations.

12.4 Biological Method Development and Application

The Method Development and Application Section is responsible for the forecasting of new test method needs within the Department, the development, validation and application of biological test methods required by departmental programs, and provides on-going support to the third-party toxicology laboratory accreditation program managed by CAEAL.

During the past two years, Section staff have had to balance test method standardization activities against a rapidly growing demand by departmental staff for assistance with the interpretation and application of toxicity test results. Method validation and standardization efforts have focused primarily on marine and freshwater sediment tests which are required by the CEPA Ocean Disposal and Great Lakes Protection programs. Guidance documents on a standard approach to sediment collection and preparation for toxicity and chemical analyses and for sediment reference toxicant testing have also been prepared in support of these departmental programs. Section staff has also been providing advice to several other Environment Canada programs (i.e. toxicity compliance provisions of the Fisheries Act pulp and paper regulations, sublethal toxicity testing requirements under the pulp and paper Environmental Efforts Monitoring (EEM) program, ocean dumpsite monitoring program, acute lethality and EEM sublethal toxicity needs for the up-coming amendment of the metal mining effluent regulations, completeness of toxicity test data submitted under the CEPA New Substances Notification Regulation, and appropriate use of toxicity testing in product assessment under the Environmental Choice� program). To aid all of the above programs, the Section initiated a project in 1994 to develop guidance on the interpretation and application of environmental toxicology data. Following considerable internal and external consultation, the guidance manual will be published in late 1996.

As well, Section staff have been very involved in the implementation of the toxicology component of the CAEAL laboratory accreditation program. Since CAEAL has limited toxicology expertise, the program relied heavily on Environment Canada staff. For example, Method Development and Application staff prepared test-specific checklists for various acute toxicity tests for use by CAEAL auditors during the 1994 &1995 laboratory inspections, conducted an auditor training session for all CAEAL toxicology auditors in 1994, participated in five toxicology laboratory inspections as volunteer auditors to CAEAL, and prepared six new auditor checklists for sublethal toxicity tests to be introduced by CAEAL in 1996 as tests for which formal accreditation can be sought.


13.0 COMMERCIALIZATION OF ENVIRONMENT CANADA’S PATENTED MICROWAVE-ASSISTED PROCESS (MAPTM)

13.1 Development of the Microwave-Assisted Processes Division
13.2 Licensing of the Various Applications of the MAP Technology
13.3 Business Plan for Privatization of the MAP Division
13.4 Enhancement of International Exposure of the MAP Technology


13.1 Development of the Microwave-Assisted Processes Division

The MAP Division at ETC was created in the fall of 1994, when the interest in MAP began to increase substantially. The Division, which was created by bringing together personnel from ESD, A&MD and EED, performs research and development on various “clean process” applications of Environment Canada’s patented Microwave-Assisted Process (MAPTM). MAP is a Trademark of Her Majesty the Queen in the Right of Canada as represented by the Minister of the Environment. The MAP technology uses microwaves and solvents which are relatively transparent to microwaves to extract chemicals from various matrices. The applications of the technology include a rapid sample preparation method for the analytical laboratory and a cost-effective replacement for conventional industrial extraction processes. When compared with conventional extraction and sample preparation methods, the MAP reduces production time, energy, solvent consumption and waste production, while increasing extraction yields and extract purity. These advantages not only reduce operating costs, but result in a more environmentally friendly process. The process has been awarded an ‘ecologoTM’ under the Environmental Choice Program.

Environment Canada, which owns the intellectual property rights for this technology in several countries, is currently investigating further applications of the technology as solutions to a number of environmental problems, such as the remediation of contaminated sites. The research and development of these techniques is performed mainly by the MAP Division in collaboration with representatives of the private, public and academic sectors. The staff of the MAP Division includes research scientists, engineers and chemists with expertise in the areas of analytical chemistry, food chemistry, and industrial and environmental technology.

13.2 Licensing of the Various Applications of the MAP Technology

To promote and implement the commercialization of the MAP applications effectively, and to provide technical support to end-users, Environment Canada currently has five licensees. CWT-TRAN International of Oakville, Ontario, and le Centre de d�veloppement Pronatex, inc. of Sherbrooke, Qu�bec, have rights in the area of large-scale industrial applications of the technology. The CEM Corporation of Matthews, North Carolina, la soci�t� PROLABO of Paris, France, and the Hewlett-Packard Company of Wilmington, Delaware, have rights in the various fields of activities that require analytical capability such as chemistry, environmental sciences, food science, forensic science, cosmetics, and so forth. The members of the MAP Division work closely with licensees and groups interested in developing and custom-tailoring new applications of MAP.

13.3 Business Plan for Privatization of the MAP Division

As stated in Environment Canada’s five year plan, the MAP Division at ETC is slated to be privatized. A detailed Business Plan for the MAPTM privatization is being developed. Such a plan was required to increase the marketability of the group, in addition to providing a better understanding of potential spin-offs from current activities and ensure a maximal return to EC. Furthermore, this precedent-setting initiative could become a model for future commercialization of government-patented technologies that Environment Canada and other departments may wish to entertain in the future.

13.4 Enhancement of International Exposure of the MAP Technology

With assistance from their licensees, the MAP Division has been able to increase the exposure of the technology throughout the world. Meetings, presentations and workshops have taken place throughout Asia, Europe and South America, as well as North America, to discuss the technology with potential users.

Following meetings between Chinese Research Academy for Environmental Sciences (CRAES) and ETC in July 1995, it was agreed that, under the umbrella of the Memorandum of Understanding between the Chinese National Environmental Protection Agency and Environment Canada, an effective method of initiating the exchange of expertise between the two Centres would be to transfer expertise related to MAP from ETC to CRAES. The purpose of this cooperative agreement is to introduce the MAP technology to China for environmental analytical chemistry applications and environmentally-friendly industrial techniques. In February 1995, workshops were held in China to present the MAP technology to potential users of the process. As well, in February 1996, a MAP pilot-plant and three laboratory-scale instruments, were sent to China and a member of the MAP Division went to CRAES to assist in the implementation of the pilot-plant and provide training to Chinese scientists. This project was partially sponsored by Environment Canada’s International Partnership Program and by the licensees, CEM Corporation and PROLABO.


14.0 DEVELOPMENT OF MAP ANALYTICAL METHODS

AND INSTRUMENTATION

14.1 Fast and ‘Green’ On-Site Characterization of Toxic Chemicals using MAP Analytical Techniques
14.2 New MAP Water Quality Measurement Technologies
14.3 Development of New MAP Laboratory-Scale Extaction Equipment


The MAP technology has applications in the liquid and gas phases, as well as in sub- and supercritical fluid conditions. Among examples of the utilization of MAP in the liquid-phase are the extraction of essential oils, aromas and flavors from plant material, extraction of polyaromatic hydrocarbons (PAHs) from polyurethane foams (PUFs) used in air monitoring, extraction of polycyclic biphenyls (PCBs) from animal tissues, as well as the extraction of a variety of analytes from solid materials, including soils and sediments. A more recent application has been the liquid-phase in situ extraction-derivatisation of phenols and methyl phenols isomers from soil samples. Another area of applications deals with the gas-phase extraction of dissolved volatile organic compounds (VOCs) in water, the analysis of aromatic chlorinated hydrocarbons in soil and others.

As a continuation of the work in further developing the MAP technology, recent progress has been made where MAP has been used under sub- and supercritical fluid conditions. Concepts and design of a bench-scale unit, that is presently under construction are also part of the MAP Division’s plans for 1996-97.

In 1995, the MAP Division also performed extensive tests in order to validate MAP as an analytical method, including to promote its acceptance as an accepted U.S. EPA method for the extraction of contaminants in various matrices including soils.

14.1 Fast and ‘Green’ On-site Characterization of Toxic Chemicals using MAP Analytical Techniques

In 1995, work was accelerated on the development of MAPTM methods to allow for the more rapid on-site characterization of toxic chemicals at waste and spill sites. The ultimate intent is to utilize the EC-patented technology to develop and eventually commercialize portable instruments that will revolutionize such work. This work is part of a joint-project agreement with the U.S. EPA.

14.2 New MAP Water Quality Measurement Technologies

In 1996, work began to develop rapid and quantitative protocols to monitor water quality, especially in terms of VOCs and other dissolved gases, more quickly and efficiently than existing technologies. The methods will apply to wastewater management, lake/river water analysis, and drinking water treatment plant monitoring.

14.3 Development of New MAP Laboratory-Scale Extraction Equipment

The companies CEM Corporation and PROLABO both have extraction units on the market, which are being sold under license to use Environment Canada’s patented microwave-assisted process. The MAP Division performed extensive research and development work using these units, and works jointly with these companies to improve the technology further and to develop more applications.


15.0 DEVELOPMENT OF INDUSTRIAL APPLICATIONS OF THE MAP TECHNOLOGY

15.1 Design, Construction, Modification and Testing of the MAP Pilot-Plant Process
15.2 Design and Construction of MAP Bench-Scale Process
15.3 MAP Industrial Product Development and Testing
15.4 Engineering: Design and Engineering Services for Pilot- and Industrial- Scale MAP Extraction Units for Various Sectors
15.5 Removal of Contaminants from Soil using the MAP Technology
15.6 Enhancement of MAP Extraction Efficiency of CO2 under Liquid and Supercritical Fluid Conditions for Industrial Purposes


15.1 Design, Construction, Modification and Testing of the MAP Pilot-Plant Process

In early 1994, the microwave portion of a MAP pilot-plant facility was designed and constructed. In the summer and fall of 1994, pre- and post-processing equipment was added to complete the pilot-plant process. The pilot-plant process consists of a 6 kW generator, a process cavity capable of continuously processing up to 900 L/hr of slurry, and ancillary material handling and separation equipment. In 1995, various tests were performed in the plant to determine the applicability of processing various products in a continuous flow, industrial system. To date, the plant has been used to test various applications of the technology, such as extraction of oils from oil seeds and natural pesticides from fresh plant material, as well as compounds that have potential biological activity.

15.2 Design and Construction of MAP Bench-Scale Process

Currently, industrial process and soil remediation applications of the MAPTM process are evaluated at laboratory scale in commercial equipment designed for small-scale analytical chemistry work. Scale-up evaluation is performed in the unique large-scale MAPTM pilot plant at ETC, but extensive work at this scale is relatively expensive and slow. In 1995, an intermediate, bench-scale MAPTM equipment was designed, and construction and purchase of the main components of the unit took place in early 1996.

The bench-scale system will be used to speed the scale-up evaluations of the process for many industrial applications. The large-scale applications of the technology promise innumerable uses as a ‘green’ industrial process, including, for example, the elimination of dichloromethane from

industrial extraction processing, while also reducing the energy consumption associated with current technologies. The same equipment will also allow accelerated assessment of the applicability of the technology for soil remediation and the extraction of useful chemicals from wastes.

15.3 MAP Industrial Product Development and Testing

Since early 1995, the MAP Division has performed evaluations of over 80 products to determine the applicability of the MAP technology to enhance the efficiency of extracting target compounds from these products. This testing was performed at the laboratory-scale to determine extraction quality and efficiencies, and to evaluate and optimize a variety of parameters for scale-up purposes. This testing was performed using two types of laboratory extraction units: CEM Corporation’s MES-1000 and PROLABO’s Soxwave-100.

For the most part, these products were brought in for testing by the MAP licensees and/or other parties interested in the applications of the technology. Example of the products tested include: flavours and fragrances from plant material, oils from seeds, natural pesticides from wood waste, natural medicines from plant material, and valuable products from waste streams.

15.4 Engineering: Design and Engineering Services for Pilot- and Industrial-Scale MAP Extraction Units for Various Sectors

Since its inception, the MAP Division has been providing engineering services to their licensees and interested parties in the design of equipment for liquid-, gas-, and critical and supercritical fluid-phase MAP extractors. The plants are custom designed, based on the product being processed and parameters selected from laboratory-scale testing. This work also involves designing MAP plants which will fit into existing installations.

15.5 Removal of Contaminants from Soil using the MAP Technology

Laboratory-scale testing has involved the removal of PCBs, phenolic compounds and PAHs from soils. Tests were also performed in conjunction with EED to investigate the use of MAP for the cleanup of soils contaminated by missile fuels. These results showed that the MAP technology could overcome some of the problems associated with current excavate and soil treatment technologies because of the increased efficiencies, shortened process times and reduced energy requirements. In 1996, further tests will be performed using the bench-scale system to evaluate the MAP soil treatment process further.

15.6 Enhancement of MAP Extraction Efficiency of CO2 under Liquid and Supercritical Fluid Conditions for Industrial Purposes

Tests have been performed at the laboratory-scale to evaluate CO2 extraction with and without the addition of microwave exposure. Preliminary results, using various plant materials, show that combining MAP with liquid CO2 conditions will give similar results to supercritical fluid extraction applications. Eliminating the requirement for high pressures required for supercritical conditions, however, greatly reduces the capital and operating costs of equipment.

APPENDIX A - Mission and Roles of the Environmental Technology Centre

Mission of the Environmental Technology Centre:

To support the Departmental national and international mandate for environmental protection by:

• developing and transferring pollution measurement, prevention, control and remediation knowledge, and new technology, in areas related to air pollution and unplanned releases of oil and hazardous materials, and

• providing relevant specialized sampling and analytical expertise and services of the highest standards.

Roles:

1. To support the regulatory role of the Department by undertaking and promoting R&D, and technology advancement and transfer, in measurement and control of air pollutant emissions, and in response to unplanned releases of oil and hazardous materials.

2. To support pollution assessment and assist in solving environmental problems associated with specific sources of air pollution or spill/waste sites which have international, national, or regional implications, by undertaking R,D&D based on in-house and external expertise and resources and cooperation with stakeholders.

3. To manage or support Departmental programs related to measurement and control of air pollution and releases of oil and hazardous materials, by providing relevant sampling, analytical, and quality assurance expertise and services.

4. To promote the better integration of economic and environmental issues and to foster a healthy and creative environmental protection industry in Canada through information and technology transfer, and support to the development of national and international technology standards and policies.

5. To advise Departmental and other clients, including the industry, provinces and territories, other R&D organisations, and the public, on environmental protection technology and emerging technical issues relating to air pollution and response to spills of oil and hazardous materials.

6. To represent the Department and Canada in federal-provincial, national, and international environmental protection technology organizations and programs and act as full partners in the international community involved with the development and application of leading-edge technology and technical standards for environmental protection relating to air pollution and control of hazardous materials.

APPENDIX B - LIST OF PATENTS, PAPERS AND REPORTS

PATENTS

Par�, J. R. J., "Microwave Extraction of Volatile Oils and Apparatus Therefor", Continuation-in-Part, filed in the Patent Office of the USA, for the USA, on March 18, 1991, abandoned in favour of Continuation-in-Part filed on March 10, 1993, issued on August 16, 1994 (No. 5 338 798).

Par�, J. R. J., "Microwave Extraction of Volatile Oils and Apparatus Therefor", Continuation-in-Part, filed in the Patent Office of the USA, for the USA - allowed.

Par�, J. R. J., "Microwave-Assisted Generation of Volatiles, of Supercritical Fluid, and Apparatus Therefor", Patent Application No. 2 060 931 - 1, priority filed in Canada on February 10, 1992 (also filed in the USA - issued on January 03, 1995 as Patent No. 5 377 426 - Japan and in the European Patent Office (France, Germany, Italy, Lichtenstein, The Netherlands, Spain, Switzerland, and The United Kingdom) - allowed.

Par�, J. R. J., "Microwave-Assisted Generation of Volatiles, of Supercritical Fluid, and Apparatus Therefor", Continuation-in-Part, filed in the Patent Office of the USA, for the USA - allowed.

Volchek, K., Mortazavi, S. and H. Whittaker, “Removal of Arsenic from Aqueous Liquids with Selected Alumina”, filed on March 4, 1993, issued on August 15, 1995 (Canadian Patent No. 2090989).

Volchek, K., Mortazavi, S. and H. Whittaker, “Removal of Arsenic from Aqueous Liquids with Selected Alumina”, filed in the Patent Office of the USA, for the USA - allowed.

TECHNICAL PAPERS/POSTERS

Akhtar, M.H., L. Croteau, J.M.R. B�langer and J.R.J. Par�, "High Performance Liquid Chromatography Determination Following Microwave-Assisted Extraction of 3-Nitro-4-Hydroxyphenylarsonic Acid from Swine Liver, Kidney and Muscle", J. Liquid Chromatog. 17, pp.2971-298, 1994.

Balgava, V., M. Tardif, C. Chiu and R. Turle, “Application of Solid-Phase Micro-Extraction for the Determination of Chlorofluorocarbons”, submitted to Journal of Chromatography, March 1996.

Bastien, C.Y., M.M. Punt and J.R.J. Par�, "Study of MAPTM Enhanced Solvent Extraction Process for the Removal of Organic Contaminants from Soil", Proceedings of the11th Technical Seminar on Chemical Spills, pp. 43-50, 1994.

B�langer, J.M.R., K. Li, M.F. Fingas, R.C. Lao, Y.Y. Shu and J.R.J. Par�, “Microwave-Assisted Process (MAPTM): A Survey of Applications”, 16th International Symposium on Capillary Chromatography, Riva del Garda, Italy, September 1994.

B�langer, A., L. Dextraze, J.M.R. B�langer and J.R.J. Par�, “Characterization of the Fragrance of Thymus vulgaris by Conventional Headspace Sampling and by MAPTM”, 16th International Symposium on Capillary Chromatography, Riva del Garda, Italy, September 1994.

B�langer, J.M.R., Y.Y. Shu, R.C. Lao, M.F. Fingas, K. Li, R.D. Turpin, R. Singhvi, D.W. Charters and J.R.J. Par�, “The Microwave-Assisted Process (MAPTM): Applications to Sample Extraction”, 78th Canadian Society of Chemistry Conference, Guelph, ON, Canada, May 1995.

B�langer, J.M.R., K. Li, M.F. Fingas, R.C. Lao, Y.Y. Shu, M.M. Punt and J.R.J. Par�, “Microwave-Assisted Process (MAPTM): A Survey of Applications to Sample Preparation”, 30th Ann. Microwave Symposium, Denver, CO, U. S. A., July 1995.

B�langer, A., L. Dextraze, J.M.R. B�langer and J.R.J. Par�, “Characterization of the Fragrance of Thymus vulgaris by Conventional Headspace Sampling and by MAPTM”, 25th International Symposium on Essential Oils, Grasse, France, September 1994.

B�langer, J.M.R., M.M. Punt, Y.Y. Shu, D. Math� and J.R.J. Par�, “The Use of the Microwave-Assisted Process (MAPTM) Under Atmospheric Pressure Conditions: A Versatile Tool for the Extraction of Flavour and Fragrances”, COLACRO VI, Caracas, Venezuela, January 1996.

B�langer, J.M.R. and J.R.J. Par�, "Proc�d� assist� par micro-ondes (MAPTM): Application au paprika", Riv. Ital. EPPOS 5, Vol. 5, pp.126-135, 1994.

B�langer, J.M.R., C. Aubry, L. Chagonda and J.R.J. Par�, “Proc�d� assist� par micro-ondes (MAPTM): Extraction d'huiles essentielles au Zimbabwe”, Riv. Ital. EPPOS 5, pp. 136-148, 1994.

B�langer, J.M.R., K. Li, M.F. Fingas, R.C. Lao, Y.Y. Shu, M.M. Punt and J.R.J. Par�, “Microwave-Assisted Process (MAPTM): A Survey of Applications to Sample Preparation, Proc. 30th Microwave Power Symposium, International Microwave Power Institute, Manassas, U. S. A., pp. 35-37, 1995.

B�langer, J.M.R., A. B�langer and J.R.J. Par�, "Proc�d� assist� par micro-ondes (MAPTM): Ol�or�sines de graines de c�leri et de poivre noir", Riv. Ital. EPPOS, Vol. 5, pp. 114-125, 1994.

B�langer, J.M.R., B. Thibert, C. Rule, T. Kierstead and J.R.J. Par�, “The Extraction of Fats From Animal Tissues Using the Microwave-Assisted Process (MAPTM) Under Atmospheric Pressure Conditions: Novel Approaches”, COLACRO VI, Caracas, Venezuela, January 1996.

Bissonnette, M.C., M.F. Fingas, R.D. Nelson, P. Beaudry and J.R.P. Par�, “Crude Oil Combustion at Sea: The Sampling of Released Products Using Remote-Controlled Boats”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1065-1081, 1994.

Bissonnette, M.C., M. Goldthorp, M.F. Fingas, J.M.R. B�langer and J.R.J. Par�, “Design and Development of a Person-Portable Instrumentation System for Emergency Response and Field Studies”, Proceedings of the 11th Technical Seminar on Chemical Spills, Environment Canada, Ottawa, Ontario, pp. 109-127, 1994.

Blenkinsopp, S., G. Sergy, Z. Wang, M.F. Fingas, J. Foght and D.W.S. Westlake, “Oil Spill Bioremediation Agents - Canadian Efficacy Test Protocols", Proceedings of the 1995 International Oil Spill Conference, American Petroleum Institute, Washington, D.C., pp. 91-96, 1995.

Brown, C.E., M. Fruhwirth and M.F. Fingas, “Airborne Oil-Spill Sensor Field Trial”, Proceedings of the First International Airborne Remote Sensing Conference and Exhibition, Environmental Research Institute of Michigan, Ann Arbor, Michigan, pp. I599-I611, 1994.

Brown, C.E., M.F. Fingas, M. Fruhwirth and R.L. Gamble, “Oil Spill Remote Sensing: A Brief Review of Airborne and Satellite Sensors”, Proceedings of the SPOT Image 1995 User Group Meeting, Washington, D.C., 14 p, 1995.

Brown, C.E., M. Fruhwirth, M.F. Fingas, R.H. Goodman, G. Vaudreuil, J-P. Monchalin, M Choquet, R. H�on, C. Padioleau and J. Mullin, “Absolute Measurement of Oil Slick Thickness: Why Do We Need to Know and How Can We Achieve It”, Proceedings of the Third Thematic Conference on Remote Sensing for Marine and Coastal Environments, Environmental Research Institute of Michigan, Ann Arbor, Michigan, pp. I491-I500, 1995.

Brown, C.E., M. Fruhwirth and M.F. Fingas, “Scanning Laser Environmental Airborne Fluorosensor: Progress on an “Exciting” Development”, Proceedings of the Third Thematic Conference on Remote Sensing for Marine and Coastal Environments, Environmental Research Institute of Michigan, Ann Arbor, Michigan, pp. I1-I5, 1995.

Brown, C.E., M. Fruhwirth, M.F. Fingas, M. Choquet, R. H�on, C. Padioleau, G. Vaudreuil, J-P Monchalin, R.H. Goodman and J.V. Mullin, “Oil Slick Thickness Measurement: A Possible Solution to a Long-Standing Problem”, Proceedings of the Eighteenth Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 427-440, 1995.

Brown, C.E., M. Fruhwirth, M.F. Fingas, R.H. Goodman, M. Choquet, R. Heon, G. Vaudreuil, J-P Monchalin and C. Padioleau, “Laser Ultrasonic Remote Sensing of Oil Thickness: Absolute Measurement of Oil Slick Thickness”, Proceedings of the First International Airborne Remote Sensing Conference and Exhibition, Environmental Research Institute of Michigan, Ann Arbor, Michigan, pp. I567-I578, 1994.

Brown, C.E., Z. Wang, M. Fruhwirth and M.F. Fingas, “May 1993 Oil Spill Sensor Test Program: Correlation of Laser Fluorosensor Data With Chemical Analysis”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1239-1261, 1994.

Canevari, G.P., R.J. Fiocco, R.R. Lessard and M.F. Fingas, “Corexit 9580 Shoreline Cleaner: Development, Application and Status”, The Use of Chemicals in Oil Spill Response, ASTM STP 1252, Peter Lane, Ed., American Society for Testing and Materials, Philadelphia, pp. 227-239, 1995.

Chiu, C. and W. Miles, “An Improved Method for Nitro-PAH Analysis”, submitted to the Proceedings of the 15th International Symposium on Polycyclic Aromatic Compounds (PAC), European Commission, Italy, September 1995.

Cooper, D., S. Penton, K. Rafuse and A.B. Nordvik, “An Evaluation of Oil Sorbent Materials”, Proceedings of the 17th Arctic and Marine Oil Spill (AMOP) Technical Seminar, Vancouver, British Columbia, June 1994.

Dabek-Zlotorzynska, E., J.F. Dlouhy, N. Houle, M. Piechowski and S. Ritchie, “Comparison of Capillary Zone Electrophoresis with Ion Chromatography and Standard Photometric Methods for the Detemination of Inorganic Anions in Atmospheric Aerosols”, J. Chromatogr., Vol. 706, pp. 469-478, 1995.

Dabek-Zlotorzynska, E. and J.F. Dlouhy, “Application of Capillary Electrophoresis in Atmospheric Aerosols Analysis: Determination of Inorganic and Organic Anions”, J. Chromatogr., Vol. 671, pp. 389-395, 1994.

Dabek-Zlotorzynska, E. and J.F. Dlouhy, “Determination of Low-Molecular Mass Organic Anions by Indirect UV Capillary Zone Electrophoresis”, Application Information, Beckman, BIC-0100, 1994.

Dabek-Zlotorzynska, E. and J.F. Dlouhy, “Capillary Zone Electrophoresis with Indirect UV Detection of Organic Anions using 2,6-Naphthalenedicarboxylic Acid”, J. Chromatogr., Vol. 685, pp. 145-153, 1994.

Dabek-Zlotorzynska, E., H. Shintani and J. Polanski, Editors, “Analytical Applications of Capillary Electrophoresis”; Chapters: “Hydrocarbons” and “Environmental Pollutants”, in press, February 1996.

Dabek-Zlotorzynska, E., M. Piechowski and J.F. Dlouhy, “Study of Adsorption Effects of Cations in Injection Loops in Ion Chromatography”, International Ion Chromatography Symposium, Dallas, TX, October 1995.

Dabek-Zlotorzynska, E. and E.P.C. Lai, “Separation of Polynuclear Aromatic Hydrocarbons by Micellar Electrokinetic Capillary Chromatography Using Sodium Taurodeoxycholate Modified with Organic Solvents”, J. Capillary Electrophoresis, in press, 1996.

Dabek-Zlotorzynska, E. and J.F. Dlouhy, “Application of Capillary Electrophoresis in Atmospheric Aerosols Analysis: Determination of Cations”, J. Chromatogr., Vol. 706, pp. 527-534, 1995.

Daykin, M., G. Sergy, D. Aurand, G. Shigenaka, Z. Wang and A. Tang, “Aquatic Toxicity Resulting From In-Situ Buring of Oil-on-Water”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, pp. 1165-1193, 1994.

Dowdall, E., M. Tardif and C. Chiu, “Automated PCB Analysis, Quantitation and Reporting”, Intern. J. Environ. Anal. Chem., Vol. 60, pp. 175-184, 1995.

Dubas, O. (Ed.), “Cleaning up Contamination at Ukrainian Missile Sites”, Canada-Ukraine Monitor, Vol.3, No.2, Spring-Summer 1995.

Fingas, M.F., “The Evaporation of Oil Spills”, Proceedings of the Eighteenth Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 43-60, 1995.

Fingas, M.F., B. Fieldhouse, L. Gamble and J.V. Mullin, “Studies of Water-in-Oil Emulsions: Stability Classes and Measurement”, Proceedings of the Eighteenth Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 21-42, 1995.

Fingas, M.F., D.A. Kyle, Z. Wang, D. Handfield, D. Ianuzzi and F. Ackerman, “Laboratory Effectiveness Testing of Oil Spill Dispersants”, The Use of Chemicals in Oil Spill Response, ASTM STP 1252, Peter Lane, Ed., American Society for Testing and Materials, Philadelphia, pp. 3-40, 1995.

Fingas, M.F., D.A. Kyle, N.D. Laroche, B.G. Fieldhouse, G. Sergy and R.G. Stoodley, “The Effectiveness Testing of Spill Treating Agents”, The Use of Chemicals in Oil Spill Response, ASTM STP 1252, Peter Lane, Ed., American Society for Testing and Materials, Philadelphia, pp. 286-298, 1995.

Fingas, M.F., D.A. Kyle, P. Lambert, Z. Wang and J.V. Mullin, “Analytical Procedures for Measuring Oil Spill Dispersant Effectiveness in the laboratory”, Proceedings of the 18th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 339-354, 1995.

Fingas, M.F., B. Fieldhouse, I. Bier, D. Conrod and E. Tennyson, “Laboratory Effectiveness Testing of Water-in-Oil Emulsion Breakers”, The Use of Chemicals in Oil Spill Response, ASTM STP 1252, Peter Lane, Ed., American Society for Testing and Materials, Philadelphia, pp. 41-54, 1995.

Fingas, M.F. and B. Fieldhouse, “Studies of Water-in-Oil Emulsions and Techniques to Measure Emulsion Treating Agents”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 213-244, 1994.

Fingas, M.F., F. Ackerman, Z. Wang, K. Li, P. Lambert, M.C. Bissonnette, G. Sergy, P. Jokuty, N. Laroche, J. Mullin, L. Hannon, R.D. Turpin, P.R. Campagna, R. Hiltabrand and D. Aurand, “In-Situ Burn Studies - The Newfoundland Offshore Burn Experiment and Further Research”, Proceedings of the Second International Oil Spill Research and Development Forum, International Maritime Organization, London, United Kingdom, pp. 465-471, 1995.

Fingas, M.F., Z. Wang, P. Jokuty, P. Lambert, G. Sergy and J. Mullin, “Oil Behaviour, Fate and Modelling Projects", Proceedings of the Second International Oil Spill Research and Development Forum, International Maritime Organization, London, United Kingdom, pp. 399-407, 1995.

Fingas, M.F., F. Ackerman, P. Lambert, K. Li, Z. Wang, J. Mullin, L. Hannon, D. Wang, A. Steenkammer, R. Hiltabrand, R.D. Turpin and P.R. Campagna, “The Newfoundland Offshore Burn Experiment: Further Results of Emissions Measurement”, Proceedings of the 18th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 915-995, 1995.

Fingas, M.F., “Studies on the Evaporation of Oil Spills”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 189-212, 1994.

Fingas, M.F., “A Literature Review of the Physics and Predictive Modelling of Oil Spill Evaporation”, Journal of Hazardous Materials, Vol. 42, pp. 157-175, 1995.

Fingas, M.F., C.E. Brown, M. Fruhwirth and L. Gamble, “Sensors for Oil Spill Remote Sensing: A Review of Performance in Use”, Proceedings of the Third Thematic Conference on Remote Sensing for Marine and Coastal Environments, Environmental Research Institute of Michigan, Ann Arbor, Michigan, pp. I19-I30, 1995.

Fingas, M.F, B. Fieldhouse and J.V. Mullin, “Water-in-Oil Emulsions: How They Are Formed and How They Are Broken”, Proceedings of the 1995 International Oil Spill Conference, American Petroleum Institute, Washington, D.C., pp. 829-830, 1995.

Fingas, M., “Chemistry of Oil and Modelling of Spills”, Journal of Advances in Marine Technology Conference, Vol. 11, pp. 41-63,1994.

Fingas, M.F., G. Halley, F. Ackerman, N. Vanderkooy, R. Nelson, M.C. Bissonnette, N. Laroche, P. Lambert, P. Jokuty, K. Li, W. Halley. G. Warbanski, P.R. Campagna, R.D. Turpin, M.J. Trespalacios, D. Dickins, E.J. Tennyson, D. Aurand and R. Hiltabrand, “The Newfoundland Offshore Burn Experiment - NOBE Experimental Design and Overview”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1053-1061, 1994.

Fingas, M.F. D.A. Kyle, Z. Wang, F. Ackerman and J. Mullin, “Testing of Oil Spill Dispersant Effectiveness in the Laboratory”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 905-941, 1994.

Fingas, M.F., G. Halley, F. Ackerman, R. Nelson, M.C. Bissonnette, N. Laroche, Z. Wang, P. Lambert, K. Li, P. Jokuty, G. Sergy, W. Halley, J. Latour, R. Galarneau, B. Ryan, P.R. Campagna, R.D. Turpin, E.J. Tennyson, J. Mullin, L. Hannon, D. Aurand and R. Hiltabrand, “The Newfoundland Offshore Burn Experiment”, Proceedings of the 1995 International Oil Spill Conference, American Petroleum Institute, Washington, D.C., pp. 123-132, 1995.

Fingas, M.F., D. Kyle and E. Tennyson, “Dispersant Effectiveness: Studies Into the Causes of Effectiveness Variations”, The Use of Chemicals in Oil Spill Response, ASTM STP 1252, Peter Lane, Ed., American Society for Testing and Materials, Philadelphia, pp. 92-132, 1995.

Fingas, M.F., F. Ackerman, K. Li, P. Lambert, Z. Wang, M.C. Bissonnette, P.R. Campagna, P. Boileau, N. Laroche, P. Jokuty, R. Nelson, R.D. Turpin, M.J. Trespalacios, G. Halley, J. B�langer, J.R.J. Par�, N. Vanderkooy, E.J. Tennyson, D. Aurand and R. Hiltabrand, “The Newfoundland Offshore Burn Experiment - NOBE - Preliminary Results of Emissions Measurement”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1099-1164, 1994.

Fingas, M.F., “Water-in-Oil Emulsion Formation: A Review of Physics and Mathematical Modelling”, Spill Science and Technology Bulletin, Vol. 2, No. 1, pp. 55-59, 1995.

Fingas, M.F., “Oil Spills and Their Cleanup”, Chemistry and Industy, No. 24, pp. 1005-1008, 1995.

Fingas, M.F., K. Li, P.R. Campagna, R.D. Turpin, F. Ackerman, M.C. Bissonnette, P. Lambert, S.J. Getty, M.J. Trespalacios, J. Belanger and E.J. Tennyson, “Emissions from In-Situ Oil Fires”, Proceedings of the Oil In-Situ Burn Workshop, U.S. Minerals Management Service, Orlando, Florida, January, pp. 39-46, 1994.

Fingas, M.F., G. Sergy, C. Brown, P. Jokuty, Z. Wang, P. Lambert, S. Blenkinsopp and B. Fieldhouse, “Research Projects of the Emergencies Science Division”, Proceedings of the Second International Oil Spill Research and Development Forum, International Maritime Organization, London, United Kingdom, pp. 687-695, 1995.

Fingas, M.F., K. Li, F. Ackerman, M.C. Bissonnette, P. Lambert, R. Nelson, G. Halley, P.R. Campagna, N. Laroche, P. Jokuty, R.D. Turpin, M.J. Trespalacios, J. Belanger, N. Vanderkooy, E.J. Tennyson, D. Aurand and R. Hiltrabrand, “The Newfoundland Offshore Burn Experiment - NOBE”, Proceedings of the Oil In-Situ Burn Workshop, U.S. Minerals Management Service, held Orlando, Florida, January, pp. 63-70, 1994.

Fingas, M.F., C.E. Brown, M. Fruhwirth and L. Gamble, “Assessment of Sensors for Oil Spill Remote Sensing”, Proceedings of the First International Airborne Remote Sensing Conference and Exhibition, Environmental Research Institute of Michigan, Ann Arbor, Michigan, pp. I1-I12, 1994.

Fruhwirth, M., C.E. Brown, M.F. Fingas and D. Green, “The Integration of Oil Spill Remote Sensing Data with an Automated Marine Navigation System”, Proceedings of the Third Thematic Conference on Remote Sensing for Marine and Coastal Environments, Environmental Research Institute of Michigan, Ann Arbor, Michigan, pp. I511-I518, 1995.

Fruhwirth, M., M.F. Fingas and C.E. Brown, “The Development of Oil Spill Laser Fluorosensors at Environment Canada”, Proceedings of the Second Thematic Conference on Remote Sensing For Marine and Coastal Environments, Environmental Research Institute of Michigan, Ann Arbor, Michigan, pp I59-I67, 1994.

Fruhwirth, M., C.E. Brown and M.F. Fingas, “Laser Fluorosensor Development: Providing Real-Time Information for Spill Response”, Proceedings of the First International Airborne Remote Sensing Conference and Exhibition, Environmental Research Institute of Michigan, Ann Arbor, Michigan, pp. I579-I585, 1994.

Harper, J., G. Sergy and T. Sagayama, “Subsurface Oil in Coarse Sediment Experiments (SOCSEX II)”, Proceedings of the 18th Arctic and Marine Oilspill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 867 - 886, 1995.

Hodgins, D.O., R.H. Goodman and M.F. Fingas, “Remote Sensing of Surface Currents in the Fraser River Plume With the SeaSonde HF Radar”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1207-1217, 1994.

Hodgins, D.O., S. E. Tinis, R.H. Goodman, M.F. Fingas and C. Bjerkelund, “Ocean Surface Feature Identification Using HF Radar in Conjunction With SAR Imagery”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1227-1237, 1994.

Hoff, R., S. Blenkinsopp, G. Sergy, C. Henry, J. Foght, Z. Wang, P. Roberts and D. Westlake, “Evaluating Biodegradation Potential of Various Oils”, Proceedings of the 18th Arctic and Marine Oilspill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1233-1241, 1995.

Huang, E.B., G. Poole and C. Chiu, “Isolation and Determination of Toxic Congeners of PCBs in Environmental Samples”, submitted to Journal of High Resolution Chromatography, March 1996.

Jokuty, P. and M.F. Fingas, “Oil Analytical Techniques for Environmental Purposes”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 245-260, 1994.

Jokuty, P., M.F. Fingas, E. Meyer, C. Knobel and S. Whiticar, “Hydrocarbon Groups and Their Relationships to Oil Properties and Behaviour”, Proceedings of the 18th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1-19, 1995.

Jokuty, P., M.F. Fingas, S. Whiticar and B. Fieldhouse, “Determination of Oil and Emulsions Viscosity and Interfacial Regimes for Standards Development”, MSRC Technical Report Number 93-030, Marine Spill Response Corporation, Washington, D.C., 70 p., 1995.

K.Volchek, S.Mortazavi, L.Lorusso, and H. Whittaker, "Removal of Lead from Contaminated Soil", Proceedings of the 11th Technical Seminar on Chemical Spills, Vancouver, June 6-7, 1994, pp. 25-42.

K.Volchek and K.Geckeler, "Removal of Hazardous Substances from Water using the Polymer-Binding Membrane-Assisted Separation Technique", submitted to Environmental Science and Technology, 1996.

Kasitsu, G.C., M.C. Bissonnette, M. Goldthorp, M.F. Fingas, J.M.R. B�langer and J.R.J. Par�, “Expansion of the Capabilities of the Person-Portable Analytical Kit (PPAK)”, Journal of Hazardous Materials, Vol. 43, pp. 129-139, 1995.

Ladanowski, C., “Standard Operating Procedures for Environment Canada Emergency Response Officers”, Proceedings of the 12th Technical Seminar on Chemical Spills, Edmonton, Alberta, June 1995.

Ladanowski, C., H. Whittaker and K. Volchek, “International Initiatives by the Emergencies Engineering Division”, Proceedings of the 12th Technical Seminar on Chemical Spills, Edmonton, Alberta, June 1995.

Ladanowski, C., “Role of Environment Canada’s Emergency Response Officers in Oil Spill Response Management”, Proceedings of 1995 International Oil Spill Conference, Long Beach, California, February 28- March 31, 1995.

Lai, E.P.C., W. Zhang, X. Trier, A. Georgi and E. Dabek-Zlotorzynska, “Speciation of Mercury by Capillary Electrophoresis with Amperometric Detection” , submitted to Anal. Chem., 1995.

Lambert, P., Z. Wang, B. Fieldhouse, P. Jokuty, M. Bissonnette, M. Fingas, S. Whiticar, D. Kyle, M. Landriault, L. Sigouin and M. Goldthorp, “Analysis of the Komineft Pipeline Oil”, Proceedings of the 18th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1187-1131, 1995.

Lambert, P.G., B.G. Fieldhouse, M.F. Fingas, S.J. Whiticar, E.J. Tennyson and J.V. Mullin, “Sampling and Analysis in the Field: Methodologies Used by the Emergencies Science Division”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 277-288, 1994.

Lao, R. C., Y.Y.Shu, J.H. Holmes, J.M.R. B�langer and J.R.J. Par�, “Air Sample Cleaning and Extraction Procedures by Microwave-Assisted Process (MAPTM) Technology”, 10th World Clean Air Congress and Exhibition, Helsinki, Finland, May 1995.

Laroche, N.D., M.F. Fingas, C. Stewart and C. Fredericks, “The Development of a Mobile Decontamination Unit for Emergency Response”, Proceedings of the 11th Technical Seminar on Chemical Spills, Environment Canada, Ottawa, Ontario, pp. 235-244, 1994.

Lawuyi, R and M.F. Fingas, “The Impact of Sulphuric Acid on the Environment”, Proceedings of the 11th Technical Seminar on Chemical Spills, Environment Canada, Ottawa, Ontario, pp. 63-99, 1994.

Lawuyi, R and M.F. Fingas, “Environmental Impact of Polychlorinated Biphenyls (PCBs) Spills and Fires”, Proceedings of the 12th Technical Seminar on Chemical Spills, Environment Canada, Ottawa, Ontario, pp. 65-98, 1995.

Legault, A., “Comparison of Two Membrane Processes for Toxic Metal Removal”, Proceedings of the 12th Technical Seminar on Chemical Spills, Edmonton, Alberta, June 1995.

Legault, A. and A.Y. Tremblay, “An Overview of the Ion Exchange/Membrane Separation Process for the Extraction of Arsenic From Water”, Proceedings of 5th Annual Symposium on Groundwater and Soil Remediation, Toronto, Ontario, October 1995.

Legault, A.S., “Etude de la r�tention d'arsenic de solutions aqueuses utilisant un traitement au polym�re suivi d'une s�paration par membrane d'ultrafiltration”, submitted to the Department of Graduate Studies of the University of Ottawa, Ottawa, Ontario, 1994.

Legault, A. and A.Y. Tremblay, “Innovative Process for Arsenic Removal Using Polymeric Binding and Membrane Separation”, 1994 Annual AIChE Meeting, San Francisco (1994)

Legault, A.S. and A.Y. Tremblay, “Arsenic Removal by Polymeric Binding and Ultrafiltration Separation”, Proceedings of the 11th Technical Seminar on Chemical Spills, Vancouver, British Columbia, June 1994.

Li, K., M.F. Fingas, J.R.P. Par�, P. Boileau, P. Beaudry and E. Dainty, “The Use of Remote-Controlled Helicopters for Air Sampling in An Emergency Response Situation”, Proceedings of the 11th Technical Seminar on Chemical Spills, Environment Canada, Ottawa, Ontario, pp. 139-158, 1994.

Li, K., M.F. Fingas, J.M.R. B�langer and J.R.J. Par�, “The Use of Thermal Extraction in Spill Response”, Proceedings of the 12th Technical Seminar on Chemical Spills, Environment Canada, Ottawa, Ontario, pp. 191-211, 1995.

Li, K., E. Dainty, M.F. Fingas, J.M.R. B�langer and J.R.J. Par�, “Remote Controlled Helicopters: A Tool for Air Sampling in Difficult Situations”, Journal of Hazardous Materials, Vol. 43, pp. 117-127, 1995.

Li, K., J.M.R. B�langer, M. Llompart, R. Singhvi, R.D. Turpin, L.B. Jassie, T. Kierstead, R.C. Lao and J.R.J. Par�, “An Evaluation of Rapid Solid Samples Extraction by the Microwave-Assisted Process (MAPTM)”, COLACRO VI, Caracas, Venezuela, January 1996.

Li, K., M.F. Fingas, J.M.R. B�langer and J.R.J. Par�, “The Vehicle-Portable Analytical System of the Emergencies Science Division of Environment Canada”, Journal of Hazardous Materials, Vol. 43, pp. 141-154, 1995.

Li, K,. M.F. Fingas, J.R.J. Par� and P. Boileau, “Determination of Dissolved Organics in the Water Soluble Fraction from Crude Oils by Headspace Analysis”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 289-306, 1994.

Li, K., M.F. Fingas, J.M.R. B�langer and J.R.J. Par�, “Evaluation of the Hewlett-Packard HP7680 Automated Supercritical Fluid Extraction System”, Proceedings of the 12th Technical Seminar on Chemical Spills, Environment Canada, Ottawa, Ontario, pp. 173-189, 1995.

Lingjun, L., Y. Chen, C. Chiu, G. Poole, W. Miles and K. Jiang, “PCDD/Fs in Sediment Samples from Chinese Schistosomiasis Areas and Potential Human Health Effects”, Proceedings of Dioxin '94 Conference, Kyoto, Japan, November 1994.

Llompart, M., K. Li, J.M.R. B�langer and J.R.J. Par�, “Gas-Phase Extraction Using the Microwave-Assisted Process (MAPTM) for the Analysis of Aromatic Chlorinated Hydrocarbons in Soil”, COLACRO VI, Caracas, Venezuela, January 1996.

Llompart, M., K. Li, J.M.R. B�langer, R. Rosa, A. Lorenzo, R. Cela and J.R.J. Par�, “Phenol Determination in Soil by In-Situ Derivatization and Extraction Using the Microwave-Assisted Process (MAP TM)”, COLACRO VI, Caracas, Venezuela, January 1996.

Llompart, M, K. Li, J.M.R. B�langer, M.F. Fingas, S.S. Blenkinsopp and J.R.J. Par�, “Gas-Phase Extraction Using the Microwave-Assisted Process (MAPTM) for the Analysis of Dissolved Volatile Organic Compounds (VOCs) in Water”, COLACRO VI, Caracas, Venezuela, January 1996.

Lorenzo, T., R. Therrien and B.O. Johannessen, “Study of Viscosity and Emulsion Effects on Skimmer Performance”, Proceedings of the 18th Arctic and Marine Oilspill Program (AMOP) Technical Seminar, Edmonton, Alberta, June 1995.

MacGregor, D.J., “Good Laboratory Practice in Canada: Past, Present and Future”, 6th North American Intl. Symposium, International Society of Quality Assurance, Phoenix, AZ, October 1995.

Mansfield, B, T. Lorenzo and H. Whittaker, “Effects of Oil Viscosity and Emulsification on Skimmer Performance”, Proceedings of Second International Oil Spill Research and Development Forum, London, U.K., May 23-26, 1995

Mansfield, B., “Can Overboard!....A Global Summary of Marine Chemical Emergencies”, Proceedings of the 11th Technical Seminar on Chemical Spills, Vancouver, B.C., June 6-7, 1994.

Mengal, P., B. Mompon, J.M.R. B�langer and J.R.J. Par�, “Proc�d� d'extraction assist�e par micro-ondes (MAPTM): Mise au point d'un pilote industriel”, Riv. Ital. EPPOS 5, pp. 106-109, 1994.

Miles, W.F., R. Thomas, C. Chiu and G. Poole, “Application of Mass Spectrometry to Environmental Samples”, Intern. J. Environ. Anal. Chem., Vol. 60, pp. 145-152, 1995.

Miller, J., D. Velicogna and H. Whittaker, “The Destruction of Hydrazine Fuels by Electrolysis”, Proceedings of the 12th Technical Seminar on Chemical Spills, Edmonton, Alberta, June 1995.

Mitchell, K., D.E. Steere, J.A. Taylor, B. Manicom, J.E. Fisher, E.J. Slenicki, C. Chiu and P. Williams, “Impact of Diesel Fuel Aromatics on Particulate PAH and Nitro-PAH Emissions”, submitted to SAE, June 1994.

Mortazavi, S., H. Whittaker, K. Volchek, A. Tremblay and F.H. Tezel, “An Advanced Process for the Removal of Arsenic from Effluents”, Proceedings of the 12th Technical Seminar on Chemical Spills, Edmonton, Alberta, June 1995.

Morton, R., S. Mortazavi, D. Cooper and A. Tremblay, “The Effect of Salt Type and Concentration on Lead Removal from Soil Using EDTA”, Proceedings of the 12th Technical Seminar on Chemical Spills, Edmonton, Alberta, June 1995.

Nejedly, Z., J.L. Campbell, W.J. Teesdale, J.R. Brook, H.A. Wiebe, R.M. Hoff, J.F. Dlouhy and T.F. Dann, “Comparison of Multielemental Analysis of Aerosol Samples by PIXE, PESA, EDXRF, and IC”, Nuclear Instruments and Methods in Physics Research B 103, pp. 473- 476, 1995.

Norden, M. and E. Dabek-Zlotorzynska, “Study of Metal-Fulvic Acid Interactions by Capillary Electrophoresis”, J. Chromatogr., in press, 1996.

Ouellette, L. and V. Razbin, “Remediation of Oil-contaminated Debris Using a Rotary Kiln Combustor”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, June 1994.

Owens, E.H., G.A. Sergy and J. Michel, “Applications of Standardized Assessment Techniques For Documenting Shoreline Oiling Conditions”, Proceedings of the 1995 International Oil Spill Conference, Washington, D.C., pp. 904-905, 1995.

Owens, E.H., B. Humphrey and G.A Sergy, “Natural Cleaning of Oiled Coarse Sediment Shorelines in Arctic and Atlantic Canada”, Spill Science and Technology Bulletin, Vol. 1, pp. 37-52, 1994.

Owens, E.H. and G. A. Sergy, “Field Guide to the Documentation and Description of Oiled Shorelines”, Environment Canada, Ottawa, Ontario, 66 p, 1994.

Par�, J.R.J., J.M.R. B�langer, M.M. Punt, Y.Y. Shu, K. Li, B. Thibert, Y. Bastien, R.C. Lao and J.R.J. Par�, “The Microwave-Assisted Process (MAPTM): Principles & Applications for the Laboratory and for Production-Scale Activities”, Full Training Course open to General Public, Beijing, Shanghai and Tianjin, China, February 1996 (Invited Plenary Lecturer for one full week).

Par�, J.R.J., J.M.R. B�langer, Y. Shu, R. C. Lao, M. Fingas, K. Li, R. D. Turpin, R. Singhvi, D. W. Charters, S. S. Stafford and D. R. Gere, “Microwave-Assisted Process (MAPTM): Applications to Sample Preparation”, 46th Pittsburgh Conference, New Orleans, LA, U. S. A., March 1995.

Par�, J.R.J., J.M.R. B�langer and S. S. Stafford, “Microwave-Assisted Process (MAPTM): a New Tool for the Analytical Laboratory”, Trends Anal. Chem 13, pp.176-184, 1994.

Par�, J.R.J., J.M.R. B�langer, K. Li, and S. S. Stafford, “Microwave-Assisted Process (MAPTM): Application to the Headspace Analysis of VOCs in Water”, J. Microcolum Sep. 7, pp. 37-40, 1995.

Par�, J.R.J., J.M.R. B�langer, R. Singhvi, R.D. Turpin, D.W. Charters and M.M. Punt, “Microwave-Assisted Extraction, Chromatgography for the Practitioner”, 34th Ann. Conf. with Short Courses, ASTM Symposium, Norfolk, VA, U.S.A., October 1995.

Par�, J.R.J., J.M.R. B�langer, R.D. Turpin, R. Singhvi, D. W. Charters, S. S. Stafford, J. Poole and M. H. Akhtar, “Analytical Applications of the Microwave-Assisted Process (MAPTM)”, 46th Pittsburgh Conference, New Orleans, LA, U. S. A., March 1995.

Par�, J.R.J., J.M.R. B�langer, R. Singhvi, R.D. Turpin, D.W. Charters, L.B. Jassie, T. Kierstead, M. Llompart, K. Li, M.M. Punt, Y.Y. Shu and R. C. Lao, “Method Development Using the Microwave-Assisted Process (MAPTM): En Route Toward a More Efficient and Responsible Sample Preparation Laboratory”, COLACRO VI, Caracas, Venezuela, January 1996.

Poole, J., F. DeMonte, J.M.R. B�langer and J.R.J. Par�, “Microwave-Assisted Process (MAPTM): A New Tool for Sample Preparation”, 45th Pittsburgh Conference, Chicago, IL, USA, March 1994.

Poole, G., B. Thibert, H. Lemaire, B. Sheridan and C. Chiu, “An Assessment of Various Aprotic Solvents to Separate PCB from Oils”, Pittcon '95, New Orleans, LA., March 1995 [also submitted for publication in Chemosphere].

Punt, M.M, C.Y. Bastien, J.M.R. B�langer, Y.Y. Shu, B. Thibert, E. Tom and J.R.J. Par�, “The Development and Evaluation of Large-Scale Industrial Applications of the Microwave-Assisted Process (MAPTM)”, Proc. 30th Microwave Power Symposium, International Microwave Power Institute, Manassas, U. S. A., pp. 18-21, 1995.

Rideout G. and J. Turner, “A Demonstration of Transit Bus Particulate Traps in Ottawa Ontario”, SAE 952651, 1995.

Rideout G. and K. Brown, “Urban Driving Cycle Test Results of Retrofitted Diesel Oxidation Catalysts on Heavy Duty Vehicles”, SAE 960134, 1996.

Rideout G., “Emissions from Methanol, Ethanol and Diesel Powered Transit Buses”, SAE 942261", 1994.

Rideout G. and Saskatchewan Research Council, “Adapting a Geo Metro to Run on Natural Gas Using Fuel-Injection Technology”, SAE Paper 951942, 1995.

Rideout G., “Heavy Duty Testing Cycles: Survey and Comparison”, SAE 942263, 1994.

Rideout G., “Evaluation of Current Natural Gas Vehicle Technology Exhaust Emissions at Various Operating Temperatures”, SAE 952437, 1995.

S.Mortazavi, K.Volchek, A.Tremblay, F.H.Tezel, and H.Whittaker, “An Advanced Process for the Removal of Arsenic from Effluents”, Proceedings of the 12th Technical Seminar on Chemical Spills, Edmonton, June 12-13, 1995, pp. 21-38.

Sergy, G., S. Blenkinsopp, J.R. Harper, B. Humphrey and E. Owens, “Recent and Emerging Canadian Studies Addressing Oil-on Shorelines Issues”, Proceedings of the Second International Oil Spill Research and Development Forum, International Maritime Organization, London, United Kingdom, pp. 388-395, 1995.

Sheridan, B.R., G. Poole, E. Dowdall and C. Chiu, “The Effect of Temperature on GPC for The Separation of PCBs from Transformer Oil and Subsequent Analysis by GC/MSD”, Intern. J. Environ. Anal. Chem., Vol. 60, pp. 195-202, 1995.

Shu, Y.Y., R.C. Lao, J.M.R. B�langer, M.F. Fingas and J.R.J. Par�, “Applications of the Microwave-Assisted Process (MAPTM) to Polyurethane Foams (PUFS) and Filters for Monitoring of Polycyclic Aromatic Hydrocarbons”, Proceedings of the12th Technical Seminar on Chemical Spills, pp. 165-171, 1995.

Shu, Y.Y., J. Holmes, J.M.R. B�langer, J.R.J. Par� and R.C. Lao, “Microwave-Assisted Process (MAPTM): Applications to Ambient Air Sample Clean-Up”, The Symposium on Capillary Chromatography and Electrophor, Wintergreen, VA, US, May 1995 (poster).

Shu, Y.Y., J.E. Dowdall, C.Chiu and R.C. Lao, “Interference of Tansformer Oil Matrices to the Internal Standards on PCB Quantification”, Intern. J. Environ. Anal. Chem., Vol. 60, pp. 185-194, 1995.

Shu, Y.Y., J. Holmes, M. Lanoy, C. Chiu, J.M.R. B�langer, J.R.J. Par� and R.C. Lao, “Air Sample Cleaning and Extraction Procedures by Microwave-Assisted Process (MAPTM) Technology”, 10th World Clean Air Congress & Exhibition, Finland, May-June 1995 (poster).

Shu, Y.Y., R.C. Lao and J.R.J. Par�, “Environmental Sample Cleaning and Extraction Procedures by Microwave-Assisted Process (MAPTM) Technology”, 17th International Symposium on Capillary Chromatography and Electrophoresis, Wintergreen, VA, U. S. A., May 1995.

Shu, Y.Y., R.C. Lao, J.M.R B�langer and J.R.J. Par�, “Microwave-Assisted Process (MAPTM): Applications to Urban Dust Analysis”, Proceedings of 12th Technical Seminar on Chemical Spills, Edmonton, AB, Canada, June 1995

Shu, Y.Y., R.C. Lao, J.M.R B�langer, M.F. Fingas and J.R.J. Par�, “Applications of the Microwave-Assisted Process (MAPTM) to Polyurethane Foams (PUFs) for Monitoring of PAHs in Air”, Proceedings of 12th Technical Seminar on Chemical Spills, Edmonton, AB, Canada, June 1995.

Singer, M., R. Tjeerdema, J. Clark, M. Sowby, D. Aurand and G.Sergy, “Croserf: Toward a Standardization of Oil Spill Cleanup Agent Ecological Effects Research”, Proceedings of the 18th Arctic and Marine Oilspill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 1263-1270, 1995.

Stafford, S.S., J.M.R. B�langer and K. Li, “Microwave-Assisted Process (MAPTM): Application to the Headspace Analysis of VOCs in Water”, 16th International Symposium on Capillary Chromatography, Riva del Garda, Italy, September 1994.

Stoev, K.N., M.K. Vutchkov, A.A. Artinian and J.F. Dlouhy, “An Analytical Expression for X-Ray Fluorescence Intensity Distribution Based on the Probability Theory”, 44th Denver X-Ray Conference, Colorado Springs, August 1995 [submitted to Advances In X-Ray Analysis, Vol. 39, 1996].

Stoev, K.N. and J.F. Dlouhy, “X-Ray Fluorescence Cross-Section Measurements in the Energy Range 4-19 ke V”, 44th Denver X-Ray Conference, Colorado Springs, August 1995 [submitted to Advances In X-Ray Analysis, Vol. 39, 1996].

Stoev, K.N., “Study of Journal Distribution of Publications In The Field of X-Ray Fluorescence Analysis”, X-Ray Spectrometry, Vol. 23, pp. 229-235, 1994.

Stoev, K.N. and J.F. Dlouhy, “Application of Multi-Element EDXRF Analysis for Study of Seasonal Variation in the Elemental Composition of Aerosols over Selected Major Cities in Canada”, 24th International Symposium on Environmental Analytical Chemistry, May 1994, Carleton University, Ottawa [CD Report 94-9, May 1994].

Tardif, M., V. Balgava, R. Turle and C. Chiu, “Novel Approaches to the Analysis of Ozone Depleting Substances in Pressurized Containers and Foams”, submitted to Intern. J. Environ. Anal. Chemistry, February 1996.

Theiss, D., B. Conlin and C. Ladanowski, “1994 Emergency Response to Dumping of DDT Canisters at the Border Pump Station, B.C.”, Proceedings of the 12th Technical Seminar on Chemical Spills, Edmonton, Alberta, June 1995.

Thornton, D.E., M.F. Fingas, H. Whittaker, B. Mansfield and G. Sergy, “Environment Canada’s Pollution Emergency R&D Program”, Proceedings of PPR’95- Prevention, Preparedness & Response to Major Industrial Accidents Involving Hazardous Substances, MIAC - Major Industrial Accidents Committee, Ottawa, Ontario, pp. 199-215, 1995.

Volchek, K., C. Ladanowski, A. Somers, H. Whittaker and A. Anantraman, “Electrolytic Decomposition of N-Nitrosodimethylamine in Water, Proceedings of the 12th Technical Seminar on Chemical Spills, Edmonton, Alberta, June 1995.

Volchek, K., C. Ladanowski, A. Somers, H. Whittaker and A. Anantraman, “Treatment of Water Contamianted with N-Nitrosodimethylamine”, Proceedings of 5th Annual Symposium on Groundwater and Soil Remediation, Toronto, Ontario, October 1995.

Volchek, K., C. Ladanowski, H.B. Hamid and H. Whittaker, “Electrolytic Decomposition of N-Nitrosodimethylamine in Water”, Proceedings of World Environmental Congress, London, Ontario, September 1995.

Volchek, K. and K. Gleckeler, “Removal of Hazardous Sustances from Water using the Polymer-Binding Membrane-Assisted Separation Technique”, Environmental Science and Technology, in press, 1996.

Volchek, K., S. Mortazavi, L. Lorusso and H. Whittaker, “Removal of Lead from Contaminated Soil”, Proceedings of the 11th Technical Seminar on Chemical Spills, Vancouver, B.C., pp. 25-42, June 1994.

Wang, Z. and M.F. Fingas, “Chemical Analysis Methods for Crude Oil”, Proceedings of the 1995 International Oil Spill Conference, American Petroleum Institute, Washington, D.C., pp. 1004-1006, 1995.

Wang, Z., M.F. Fingas and K. Li, “Fractionation of a Light Crude Oil and Identification and Quantitation of Aliphatic, Aromatic and Biomarker Compounds by GC-FID and GC-MS, Part II”, Journal of Chromatographic Science, Vol. 32, pp. 361-382, 1994.

Wang, Z., M.F. Fingas and G. Sergy, “Chemical Characterization of Crude Oil Residues from an Arctic Beach by GC/MS and GC/FID”, Proceedings of the 18th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 111-139, 1995.

Wang, Z. and M.F. Fingas, “Identification of Alkyl Benzenes and Direct Determination of BTEX and (BTEX + C3-Benzenes) in Oils by GC/MS”, Proceedings of the 18th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 141-164, 1995.

Wang, Z., M.F. Fingas, M. Landriault, L. Siqouin and N. Xu, “Identification of Alkyl Benzenes and Direct Determination of BTEX and (BTEX + C3-Benzenes) in Oils by GC/MS”, Analytical Chemistry, Vol. 67, No. 19, pp. 3491-3500, 1995.

Wang, Z., M.F. Fingas and G. Sergy, “Chemical Characterization of Crude Oil Residues from an Arctic Beach by GC/MS and GC/FID”, Environmental Science and Technology, Vol. 29, No. 10, pp. 2622-2631, 1995.

Wang, Z. and M.F. Fingas, “Use of Methyldibenzothiophenes as Markers for Differentiation and Source Identification of Crude and Weathered Oils”, Environmental Science and Technology, Vol. 29, No. 11, pp. 2842-2849, 1995.

Wang, Z. and M.F. Fingas, “Differentiation of the Source and Monitoring of the Oil Weathering Process Using Gas Chromatography - Mass Spectrometry", Journal of Chromatography A, Vol. 712, pp. 321-343, 1995.

Wang, Z., M.F. Fingas and K. Li, “Fractionation of a Light Crude Oil and Identification and Quantitation of Aliphatic, Aromatic and Biomarker Compounds by GC-FID and GC-MS, Part I”, Journal of Chromatographic Science, Vol. 32, pp. 361-366, 1994.

Wang, Z. and M.F. Fingas, “Study of the Effects of Weathering on the Chemical Composition of a Light Crude Oil Using GC/MS GC/FID”, Journal of Microcolumn Separations, Vol. 7 (6), pp. 617-639, 1995.

Wang, Z. and M.F. Fingas, “Using Biomarker Compounds to Track the Source of Spilled Oil and to Monitor the Oil Weathering Process”, LC-GC- The Magazine of Separation Science, Vol. 13 (12), pp. 950-959, 1995.

Wang, Z. and M.F. Fingas, “Study of the Effects of Weathering on the Chemical Composition of a Light Crude Oil”, Proceedings of the17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 133-171, 1994.

Wang, Z., M.F. Fingas and G. Sergy, “Study of 22-Year-Old ARROW Oil Samples Using Biomarker Compounds by GC/MS”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 93-131, 1994.

Wang, Z.and M.F. Fingas, “Quantitative Oil Analysis Method”, Proceedings of the 17th Arctic and Marine Oil Spill Program Technical Seminar, Environment Canada, Ottawa, Ontario, pp. 307-335, 1994.

Wang, Z., M.F. Fingas and G. Sergy, “Study of 22-Year-Old ARROW Oil Samples Using Biomarker Compounds by GC/MS”, Environmental Science and Technology, Vol. 28, No. 9, pp. 1733-1746, 1994.

Wang, Z. and M.F. Fingas, “Analysis of Sorbitan Ester Surfactants: Part 2.Capillary Supercritical Fluid Chromatography”, Journal of High Resolution Chromatography, Vol. 17, pp 85-90, 1994.

Wang, Z. and M.F. Fingas, “Analysis of Sorbitan Ester Surfactants: Part 1.High Performance Liquid Chromatography”, Journal of High Resolution Chromatography, Vol. 17, pp 15-19, 1994.

EE MANUSCRIPT SERIES OF ENVIRONMENT CANADA

Bastien, C.Y., “The EED Solvent Extraction Process For the Removal of Petroleum-Derived Hydrocarbons From Soil”, Manuscript Report EE-148, Environment Canada, Ottawa, Ontario, 50 p, 1994.

Harper, J.R. and F. Harvey-Kelly, “Subsurface Oil Retention in Coarse Sediments Beaches”, Manuscript Report EE 147, Environment Canada, Ottawa, Ontario, 70 p, 1994.

Harper, J.R. and M. Kory, “Stranded Oil in Coarse Sediment Experiments (SOCSEX II), Manuscript Report EE-155, Environment Canada, Ottawa, Ontario, 124 p, 1995.

Harris, G., “The Comparative Toxicity of Crude and Refined Oils to Daphnia magna”, Manuscript Report EE-152, Environment Canada, Ottawa, Ontario, 23 p, 1994.

Hodgins, D.O., “Surface Current Measurements in Juan de Fuca Strait Using the SeaSonde HF Radar”, Manuscript Report EE-149, Environment Canada, Ottawa, Ontario, 70 p & appendices, 1995.

Hodgins, D.O., J.S. Hardy and S.E. Tinis, “Remote Sensing of Surface Currents in the Fraser River Plume With the SeaSonde HF Radar”, Manuscript Report EE-151, Environment Canada, Ottawa, Ontario, 57 p & appendices, 1994.

Humphrey, B., “Stranded Oil in Coarse Sediments (SOCS) Model”, Manuscript Report EE-146, Environment Canada, Ottawa, Ontario, 27 p, 1994.

Jokuty, P., S.Whiticar, M. Fingas, Z. Wang, K. Doe, D. Kyle, P. Lambert and and B. Fieldhouse, “ Orimulsion: Physical Properties, Chemical Composition, Dispersibility and Toxicity”, Manuscript Report EE-154, Environment Canada, Ottawa, Ontario, 31 p., 1995.

Jokuty, P., M. Fingas, S.Whiticar and B. Fieldhouse, “A Study of Viscosity and Interfacial Tension of Oils and Emulsions”, Manuscript Report EE-153, Environment Canada, Ottawa, Ontario, 43 p., 1995.

SPILL TECHNOLOGY NEWSLETTER OF ENVIRONMENT CANADA

Blenkinsopp, S., G. Sergy, P. Boileau, D. Kyle and D. Aurand, “The Development of a Standard Method For Producing Water Accommodated Fractions From Petroleum Hydrocarbons For Aquatic Toxicity Testing”, Spill Technology Newsletter, Vol. 19, pp. 1-8, 1994.

Fingas, M.F. and B. Mansfield, ‘A Review of Oil Spill Countermeasures”, Spill Technology Newsletter, Vol. 19, No.4, pp. 1-8, 1995.

Fingas, M.F., G. Sergy, Z. Wang, C. Brown, P. Jokuty, P. Lambert, B. Fieldhouse and S. Blenkinsopp, “Oil Spill Research Projects of the Emergencies Science Division”, Spill Technology Newsletter, Vol. 19, No.3, pp. 1-10, 1994.

Sergy, G. and E. Owens, “The Development of Shoreline Cleanup Assessment Procedures in North America”, Spill Technology Newsletter, Vol 19, pp. 1-6, 1994.

EPS REPORT SERIES OF ENVIRONMENT CANADA

Environment Canada, "National Air Pollution Surveillance (NAPS) Annual Summary for 1992", EPS7/AP/25, July 1994.

Environment Canada, “Guidance Document on Collection and Preparation of Sediments for Physicochemical Characterization and Biological Testing”, Report EPS 1/RM/29,

December 1994.

Environment Canada, “Guidance Document on Measurement of Toxicity Test Precision Using Control Sediments Spiked with a Reference Toxicant”, Report 1/RM/, Available Mid-1996.

Environment Canada, “Guidance Document for Statistical Determination of Toxicity Test Endpoints”, Report 1/RM/, Available Late 1997.

Environment Canada, “Guidance Document on Interpretation and Application of Environmental Toxicological Data”, 1/RM/, Available Late 1996.

Environment Canada, “Biological Test Method: Test for Growth and Survival in Sediment Using Larvae of Freshwater Midges (Chironomus tetans or Chironomus riparius)”Report 1/RM/, Available Fall 1996.

Environment Canada, “Biological Test Method: Test for Growth and Survival in Sediment Using the Freshwater Amphipod Hyalella azteca” Report 1/RM/, Available Fall 1996.

MANUSCRIPT REPORTS (Unedited)

Balgava, V., “Interim Report: Application of the Short Path Thermal Desorption for the Determination of CFCs in Foams”, A&MD Report 96-1, January 1996.

Barton P., “The Effects of Aged Catalysts and Cold Ambient Temperature on Nitrous Oxide Emissions”, Report series MSED 94-21, 1994.

Barton P., “Ecology Pure Air ‘CEM’ Catalyst Evaluation”, Report Series MSED 94-26731, 1995.

Barton P., “RXP Evaluation”, Report Series MSED 95-26741, 1995.

Beak Consultants Limited, “Method Development for Acute Toxicity Testing Using Marine Invertebrates From the Canadian Arctic” Prepared for R.P. Scroggins, Method Development and Application Section, Environment Canada, TS-30 March 1995.

Bonnell Environmental Consulting, “Assessment of Soil Toxicity Test Species for Canadian Representativeness”, Prepared for R.P. Scroggins, Method Development and Application Section, Environment Canada, TS-28 August 1994.

Buist, I., S. Potter, D. Cooper, A. Nordvik and J. Simmons, “Pressure Drops Associated with Pumping Water-in-Oil Emulsions”, Internal Report, 1994.

Cianciarelli, D., “Characterization of Semi-volatile and Volatile Organic Compounds From a Recovery Boiler - Les Cartons St-Laurent, La Tuque, Qu�bec”, PMD In-house report, March 1995.

Craig, A., “Evaluation of the Zimac Preheater Module for Catalytic Converters”, Report Series MSED 94-12, 1994.

Craig A., “Evaluation of the Fu Chin-Gelly Magnetic Oil Filter on a 1992 Volkswagen Eurovan”, Report Series MSED 94-26732, 1994.

Dabek-Zlotorzynska, E., M. Piechowski, C. Rule and J.F. Dlouhy, “Canadian Acid Aerosol Measurement Program (CAAMP); Major Anions, Ammonium and pH Analysis in the Extracts of Filters and Denuders”, 3rd Quality Control Report, CD 95-02, March 1995.

Dabek-Zlotorzynska, E. and J.F. Dlouhy, “Long Range Transport of Atmospheric Pollutants Study 35, 36 and 37; Ecosystem Interlaboratory QA Program Study FP64 and FP65”, Executive Summary, CD Report 95-01, February 1995.

Dabek-Zlotorzynska, E., N. Houle and J.F. Dlouhy, “NAPS Program; Analysis of Ions in Atmospheric Aerosols by Multi-Dimensional Ion Chromatography”, Quality Control Report, CD Report 94-7, March 1994.

Dann, T., “Detroit Incinerator Monitoring Program - Data Report #7 PCDD/PCDF Data Analysis for July 1987 to April 1994”, PMD In-house report, January 1995.

Dann, T., “Ambient Air Measurements of Benzene at Canadian Monitoring Sites (1987-1993)”, PMD In-house report, July 1994.

Dann, T., “PM10 and PM2.5 Concentrations at Canadian Sites : 1984 - 1993”, PMD In-house report, November 1994.

Dumouchel, F. and P. Hennigar, “Canadian Shellfish Contaminants Monitoring QA/QC Analytical Guidelines”, Prepared for Laboratory Managers’ Committee, Environment Canada July 1995.

Environment Canada, “Guidance on Interpretation of Sublethal Toxicity Test Data Generated for the Environmental Effects Monitoring (EEM) Program Under the Pulp and Paper Effluent Regulation, October 1995.

Fearn J., “Exhaust Emissions Testing of Clean Air Valve”, Report Series MSED 94-17, 1994.

Fearn J., “World of Wheels 94", Report Series MSED 94-22, 1994.

Fearn J., “Exhaust Emissions Testing of FuelMax Retrofit Device”, Report Series MSED 94-18, 1994.

Graham, L., “Emissions Characterization of a Fleet of 1993 Model Year Light Duty Vehicles”, Report Series MSED 94-13, 1995.

Graham L., “Underground Garage Air Quality Assessment Program”, Report Series MSED 94-29, 1995.

Graham L., “Detailed Characterization of the Emissions from a Perkins Phaser Diesel Engine”, Report Series MSED 95-07, 1995.

Graham L., “Contribution to Curbside Air Quality from Mobile Sources”, Report Series MSED 94-28, 1995.

Hamr, P., R.S. Kirby, P. Gillis and K. Day, “Development of Methodologies for Whole Sediment Toxicity Tests with Benthic Invertebrates” (a.) Optimum age for initiation and duration of the Hyalella aztec survival and growth test (b.) Formulation of artificial

sediment(s) for use in reference toxicity tests with benthic invertebrates, Prepared for R.P. Scroggins, Method Development and Application Section, Environment Canada, TS-27 July 1994.

Hendren F., “MSED Paper to Support Environmental Industry”, Report Series MSED 94-30, 1995.

Hendren F., “Evaluation of the Fuel Heater 2000 for Fuel Consumption and Exhaust Emissions Reductions in a Heavy Duty Vehicle Application”, Report Series MSED 94-19, 1994.

Hendren F., “Evaluation of Tall Oil Biodiesels on Diesel Engine Exhaust Emissions”, Report Series MSED 95-26744, 1995.

Howes P., “Emissions Deterioration Assessment of Bi-Fuel Natural Gas Vehicles”, Report Series MSED 94-24, 1994.

Howes P., “Environment Canada-Petro Canada RVP Program-Phase 1 Oldsmobile Eighty Eight”, Report Series MSED 94-26, 1994.

Howes P., “Emission Optimization/Calibration of GFI Equipped Bi-Fuel LPG Fuelled Vehicles”, Report Series MSED 94-16, 1994.

Howes P., “Evaluation of a Biodiesel Powered by a DDECII 8V71 Engine”, Report Series MSED 95-26743-2, 1995.

Howes, P. and F. Hendren, “Evaluation of Fuel Injectors and a Fuel Catalyst Device on Exhaust Emissions from a Diesel Fueled 6V53", Report Series MSED 94-20, 1994.

Huang, E.B., “Interim Report: Isolation and Determination of Non-Ortho Substituted Chlorobiphenyls by HPLC: A Literature Review”, A&MD Report 95-5, November 1994.

Huang, E.B., “Interim Report: Cleanup of Polycyclic Aromatic Hydrocarbons (PAHs) and Nitro-PAHs in Environmental Samples by Solid Phase Extraction: (Literature Review)”, A&MD Report 95-6, August 1995.

Huang, E.B., G. Poole and C. Chiu, “Clean-Up of Polycyclic Aromatic Hydrocarbons (PAHs) in Environmental Samples by Solid Phase Extraction”, A&MD Report 96-2, February 1996 (in preparation).

Ladanowski, C. (coordinated), “ETC Biennial Report : April 1, 1992 to March 31, 1996”, Report Series DO 94-1, August 1994.

Mar, J., “NAPS - QA/QC Guidelines”, PMD In-house report, December 1995.

McCuaig K., “Evaluation of Emissions from Diesel Engines During Idling Conditions Versus Engine Shut Off”, Report Series MSED 95-01, 1995.

McQuaker, N.R. and R.Turle, “Environmental Testing and Accreditation Initiatives in Canada, Mexico and the United States”, A&MD Report 95-03, April 1995.

Mortazavi, R., “Report on the Emissions of Freon 12 and Freon 113 from the HALOZONE Recovery Unit at the National Archives of Canada Deacidification Process”, PMD In-house report, November 1994.

Mortazavi, R., “Characterization of Semi-volatile Organic Compounds from an Air Transportable Incinerator - Les �les de la Madeleine, Qu�bec”, PMD In-house report, September 1995.

Mortazavi, R. and J. Williams, “Characterization of Greenhouse Gases and Volatile Organic Compounds from Vented Landfill Gases”, PMD In-house report, August 1995.

Nikolic Z., “1995 Cross Correlation Program for Clayton ECE-50 vs Electric Chassis Dynomometer”, Report Series MSED 95-02, 1995.

Pocklington, P., K. Doe, D.McLeay, M. Pocklington, S. Wade, D. Huybers, M. Lee and M. Fennell, “Development of Environment Canada’s Growth-and-Survival Test for Sediment Toxicity Using Cultured Polychaete Worms”, Prepared for R.P. Scroggins, Method Development and Application Section, Environment Canada, December 1995.

Radnoff, D. and C. Ladanowski, “Phase I Environmental Site Assessment for NCC Properties on Montcalm Street along Brewery Creek, Hull, Quebec”, prepared for NCC, May 1995.

Rideout G., “Exhaust Emissions from a Feedback Controlled Fuel Injected Natural Gas Vehicle”, Report Series MSED 94-25, 1994.

Rideout G., “Cargo Studies on Marine Tank Vessels”, Report Series MSED 94-31, 1995.

Rideout G., “Emissions Testing from Ships”, Report Series MSED 95-05, 1995.

Rideout G., “Evaluation of a Biodiesel Powered by a 1988 DDECII 6V92 TA Engine”, Report Series MSED 95-26743-1, 1995.

Rideout, G., “Emissions Evaluation of a Fuel Injected Natural Gas Suzuki Turbo Sprint”, Report Series MSED 95-26759, 1996.

Rideout G., “Emissions Evaluation of Oxidation Catalysts on a Medium Duty Diesel Truck”, Report Series MSED 95-26757, 1995.

Rideout G., 93"An Evaluation of Exhaust Emissions and Fuel Economy from a Diesel Electric Hybrid Bus”, Report Series MSED 95-26751, 1995.

Rideout G., “Emissions Testing of a Dual Fueled Diesel-Natural Gas Transit Bus-Track Test”, Report Series MSED 94-23, 1994.

Rosenblatt D., “Joint Transport Canada - Environment Canada Study to Investigate Mobile Source Emissions at the Macdonald-Cartier International Airport, Ottawa”, Report Series MSED 94-14, 1994.

Rosenblatt D., “Characterization of Emissions from Small Utility Engines Using Reformulated Fuels”, Report Series MSED 95-06, 1995.

Rule, C. and E.P.C. Lai, “Micellar Electrokinetic Chromatography (MEKC) of Polynuclear Aromatic Hydrocarbons (PAHs)”, A&MD Report 95-04, April 1995.

Shu, Y.Y., “Environmental Sample Cleaning and Extraction Procedures by Microwave-Assisted Process (MAPTM) Technology”, CD Report 94-12, August 1994.

Shu, Y.Y., R.C. Lao, J.H. Holmes and J.R.J. Par�, “MAPTM: Microwave-Assisted Process in the Analysis of PAHs in PUFs - Part IV”, Report Series DO-04, Environment Canada, 17 p., 1994.

Shu, Y.Y., R.C. Lao, J.H. Holmes and J.R.J. Par�, “MAPTM: Microwave-Assisted Process in the Analysis of PAHs in PUFs - Part V”, Report Series DO-05, Environment Canada, 8 p., 1994.

Souligny M., “Emissions and Performance Study of University of Alberta Hybrid Vehicle”, Report Series MSED 94-32, 1994.

Souligny M., “Performance and Emissions from the Hybrid Electric Vehicle HEVCAR Fabricated by the University of Alberta”, Report Series MSED 95-03, 1995.

Tardif, M. and C. Chiu, “Isomer-Specific Analysis of PAH in Ambient Air Samples”, A&MD Report 96-3, February 1996 (in preparation).

Willams, B and J. Williams, “Measurement of Emission Rates of Selected Landfill Gases from Municipal Solid Waste Landfills”, PMD In-house report, April 1995.

Williams, J., “Characterization of Vented Landfill Gases - Progress Report”, PMD In-house report, March 1995

Williams, B., “Report on the Long Term Evaluation of a Pilot Scale SCR Reactor for the Control of Nitrogen Oxides from a Coal-Fired Boiler”, PMD In-house report, September 1995.

Wittorff, D., A. Gertler, R. McLaren, W. Belzer and T. Dann, “Characterization of Vehicle Emissions in the Cassiar Tunnel, Vancouver, B.C.”, PMD In-house report, December 1994.

APPENDIX D - ABBREVIATIONS

ABB Asea Brown Boveri

AES Atmospheric Environment Service

AMOP Arctic & Marine Oilspill Program

ARET Accelerated Reduction & Elimination Toxics

ASTM American Society for Testing and Materials

BOSS Behaviour of Spilled Oils

CAAMP Canadian Acid Aerosol Measurement Program

CAEAL Canadian Association of Environmental Analytical Laboratories

CANMET Canada Centre for Mineral and Energy Technology

CCME Canadian Council for Ministers of the Environment

CD Chemistry Division

CE Capillary electrophoresis

CEA Canadian Electrical Association

CEM Continuous Emissions Monitoring

CEPA Canadian Environmental Protection Act

CFB Canadian Forces Base

CIDA Canadian International Development Agency

CTEMP Canadian Trace Emissions Management Project

DAWG Data Analysis Working Group

DGM Dry gas meter

DND Department of National Defence

EARP Environmental Assessment and Remediation Project

ECEP Environmental Centre of Excellence Project

ECS Environmental Conservation Service

EDTA Ethylene diamine tetracetate

EED Emergencies Engineering Division

EEM Environmental Efforts Monitoring

EPA Environmental Protection Agency

EPRI Electrical Power Research Institute

EPS Environmental Protection Service

ESD Emergencies Science Division

ETC Environmental Technology Centre

FID Flame Ionization Detector

FMI Fenco MacLaren Inc.

GC Gas chromatography

GDRRA Greater Detroit Municipal Incinerator

GFI Gaseous Fuel Injection

GHG Greenhouse gas

GLII Gartner Lee International Inc.

GLP Good Laboratory Practice

HPLC High pressure liquid chromatography

HRMS High-resolution mass spectrometry

IC Ion Chromatography

ICBM InterContinental Ballistic Missile

JPA Joint Project Agreement

LEV Low emission vehicle

LFG LandFill gas

LPG Liquefied petroleum gas

LMC Laboratory Managers' Committee

LRMS Low-resolution mass spectrometry

LRTAP Long-Range Transportation of Air Pollution

MAP Microwave Assisted Process

MOG Mineral oil and grease

MS Mass spectrometry

MSED Mobile Sources Emission Division

MSW Municipal Solid Waste

MTBE Methyl tertiary butyl ether

MVSA Motor Vehicle Safety Act

NAPS National Air Pollution Surveillance

NDMA n-nitrosodimethylamine

NOBE Newfoundland Offshore Burn Experiment

NOx Nitrogen oxides

NPT Nuclear Non-Proliferation Treaty

NRCan Natural Resources Canada

OBI Ontario Bus Industries

ODS Ozone Depleting Substance

OECD Organisation for Economic Co-operation and Development

OETF Oil Engineering Test Facility

OPA 90 Oil Pollution Act, 1990

PAH Polycyclic aromatic hydrocarbon

PAMI Prairie Agricultural Machinery Institute

PAPRICAN Pulp & Paper Research Institute of Canada

PCB Polychlorinated biphenyl

PCDD Polychlorinated dibenzo-p-dioxins

PCDF Polychlorinated dibenzofurans

PERD Panel on Energy Research and Development

PIR Pollution Incident Report

PISCES Power Plant Integrated Systems Chemical Emissions Study

PM Particulate mass

PMD Pollution Measurement Division

PVC Polyvinyl chloride

QA Quality assurance

QC Quality control

R&D Research and Development

RVP Reid Vapour Pressure

SCAT Shoreline Cleanup Assessment Team

SCR Selective Catalytic Reduction

SPME Solid Phase MicroExtraction

TEQ Toxic equivalent

THC Total hydrocarbon

TPH Total petroleum hydrocarbons

TSD Transportation Systems Division

TSOCS Technical Seminar on Chemical Spills

UDMH Unsymmetrical dimethylhydrazine

UV Ultraviolet

VC Vinyl chloride

VOC Volatile organic compound

VOST Volatile Organic Sampling Train

WOSM World Oil Spill Model


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